A comparison of the determined thermodynamic dissociation parameters for [Cu(py)4(NO3)2]·2py with those for analogous Mn, Co, Ni and Zn clathrates indicates the stability of the host molecules as the main contribution to the stability of the resulting clathrates....
The combined results of 10 acute toxicity experiments, each testing the joint toxicity of two of the ions Cu2+, Cd2+, Zn2+, Mg2+, and K+, were examined in terms of different response surface models which could be used to make decisions a... BGED March - 《Canadian Journal of Fisheri...
Collision-induced dissociation and theoretical studies of Cu+-dimethoxyethane complexes Collision-induced dissociation of the dimethoxyethane (DXE) complexes with copper ions, Cu +(DXE) n, n = 1 and 2, is studied using kinetic energy dependent... H Koizumi,PB Armentrout - 《Journal of the Ameri...
To better understand the layered material, the chemical formula of ZnAl-LDHs has been written as [Zn2Al(OH)6]NO3·nH2O (Scheme S1A). Then, by substituting for the interlayer NO3− anions, EDTA was loaded by the mechanism of electrostatic attraction between the positive-charged ZnAl-layer...
The synthesis of the MoNi4 electrocatalyst involves two steps, as illustrated in Fig. 1. First, the NiMoO4 cuboids were grown beforehand on a piece of nickel foam (1 Â 3 cm2) via a hydrothermal reaction at 150 °C for 6 h in 15 ml of deionized water containing Ni(NO3)26H2O ...
The comparison of the thermodynamic dissociation parameters for the [MPy4(NO3)2]*2Py series with M = Mn, Co, Ni, Cu, Zn and Cd shows that the differences in the stability of the compounds do not correlate with structural parameters of the clathrates but depend on the nature of the ...
Loss of DMSO+ is computed to be exothermic for n = 13, the exothermicity decreasing as n increases. The singly charged complexes in the ESI spectra were [CuX(DMSO)n]+ (X = Cl, Br, NO3, HSO4, n = 1 or 2). The CAD spectra showed competition between electron transfer from anion ...