ChemistryselectMaru, M.S.; Ram, S.; Adwani, J.H.; Shukla, R.S. Selective and Direct Hydrogenation of CO2 for the Synthesis of Formic Acid over a Rhodium Hydrotalcite (Rh-HT) Catalyst. ChemistrySelect 2017, 2, 3823-3830. [CrossRef]...
Here, we propose an unusual CO2activation pathway that, through a weakly bonded carbamate zwitterion complex on the Schiff-base-mediated gold catalyst, can effectively avoid the thermodynamic sink of the conventional bicarbonate reactant, and lead to the direct hydrogenation of CO2to formate. Results ...
The direct hydrogenation of CO2into methanol is crucial for providing a means of CO2fixation and a way to store cleanly produced hydrogen in a more energy-dense and transportable form. Here we have prepared two series of Pd/ZnO catalysts, both by immobilisation of PVA-protected Pd colloids and...
The selective hydrogenation of CO2 to value-added chemicals is attractive but still challenged by the high-performance catalyst. In this work, we report that gallium nitride (GaN) catalyzes the direct hydrogenation of CO2 to dimethyl ether (DME) with a C
Although considerable progress has been made in carbon dioxide (CO2) hydrogenation to various C1 chemicals, it is still a great challenge to synthesize value-added products with two or more carbons, such as gasoline, directly from CO2 because of the extreme inertness of CO2 and a high C–C ...
While direct hydrogenation of CO2 is seen as very promising for methanol synthesis on an industrial scale, as it is thermodynamically more favourable than rWGS [7], the indirect route via rWGS and CO is reported to give a 20 % higher methanol yield compared to direct hydrogenation [4]. ...
Hydrogenation of CO2 to methanol over Cu/AlCeO catalystShaozhong Li aLimin Guo aTatsumi Ishihara b cCatalysis Today
The direct hydrogenation of CO2 using H2 gas is a one-stone-two-birds route to produce highly value-added hydrocarbon compounds and to lower the CO2 level ... HHW A,SNZ A,TJZ A,... - 《Science Bulletin》 被引量: 0发表: 2020年 加载更多来源...
The direct hydrogenation of CO2 using H2 gas is a one-stone-two-birds route to produce highly value-added hydrocarbon compounds and to lower the CO2 level ... DJ Schingoethe,GL Beardsley 被引量: 0发表: 0年 Analysis of cretaed value added in the electric power sector: a case study of...
Propanol is formed through a sequence of reactions starting with reverse water鈥揼as shift to reduce CO2 to CO, which is further consumed in the hydroformylation of ethylene to propanal. The latter is finally hydrogenated to propanol, while propanol hydrogenation to propane is suppressed.doi:10.1002...