联亚胺法还原(Diimide Reduction) 联亚胺法还原通常是把炔烃还原成Z-烯烃的方法。一般情况下,联亚胺都是现做现用。 基本文献 ・Annunziata, R.; Fornasier, R.; Montanari, F.J. Org. Chem.1974,39, 3195. DOI:10.1021/jo00936a003 ・Cusack, J.; Reese, B.; Risius, C.; Roozpeikar, B.Tetrahe...
The results of many stereochemical studies have indicated that diimide approaches from the less sterically hindered side of thedouble bond,i.e.steric approach control dominates thestereoselectivityof thediimide reductionreaction. This is consistent with the rather exothermic nature of the reaction,12which...
联亚胺法还原(Diimide Reduction)2014/8/7 还原反应 Z-烯烃产物, 联亚胺 Author: LuWenjie 概要 联亚胺法还原通常是把炔烃还原成Z-烯烃的方法。一般情况下,联亚胺都是现做现用。 基本文献 ・Annunziata, R.; Fornasier, R.; Montanari, F. J. Org. Chem. 1974, 39, 3195. DOI: 10.1021/jo00936a003 ...
联亚胺法还原(Diimide Reduction) 联亚胺法还原通常是把炔烃还原成Z-烯烃的方法。一般情况下,联亚胺都是现做现用。 基本文献 ・Annunziata, R.; Fornasier, R.; Montanari, F.J. Org. Chem.1974,39, 3195. DOI:10.1021/jo00936a003 ・Cusack, J.; Reese, B.; Risius, C.; Roozpeikar, B....
Tran Dai Nang,Katabe, Yasuo,Minoura, Yuji.DIIMIDE REDUCTION OF CIS-1,4-POLYISOPRENE WITH p-TOLUENESULPHONYLHYDRAZIDE.Polymer. 1976DIIMIDE REDUCTION OF CIS-1,4-POLYISOPRENE WITH p-TOLUENESULPHONYLHYDRAZIDE. Tran Dai Nang,Katabe, Yasuo,Minoura, Yuji. Polymer . 1976...
Keywords: reviews; generation in situ; dideuteriodiimide; reduction of aldehydes and ketones; reduction of allenes; selective reduction; isolation; reduction of double and triple bonds; reduction; reduction of alkenes; generation; selective reduction of unsaturated endoperoxides...
S. HünigChemisches Institut der Universität Würzburg (Germany)Hans Richard MüllerChemisches Institut der Universität Würzburg (Germany)John Wiley & Sons, LtdAngewandte Chemie International Edition in EnglishHünig, S.; Müller, H. R. (Angew. Chem. 74 [1962] 215/6; Angew. Chem. Int. ...
Diimide reduction of olefins, an alkyne and an azo compound using C5H5I(OAc)2/CH2Cl2 at room temperature is reported.doi:10.1080/00397918708075744Moriarty, Robert M.Vaid, Radhe K.Duncan, Michael P.Taylor & FrancisSynthetic CommunicationsMoriarty, R. M.; Vaid, R. K.; Ducan, M. P., ...
A one-pot protocol for the formation of 2-nitrobenzenesulfonylhydrazide (NBSH) from commercial reagents and sub- sequent alkene reduction is presented. The transformation is operationally simple and generally efficient for effecting diimide alkene reductions. A range of 16 substrates have been reduced,...
The onset oxidation/reduction potentials (φox/red) can be obtained from the cyclic voltammograms, as shown in Fig 1d. According to the equations of EHOMO/LUMO = −e (φox/red − φFc+/Fc + 4.8) (eV), the ELUMO value was calculated to be −3.78 eV for PD...