dihedral angleuniformly intermixed grain-matrix aggregatenumerical analysisrhombic dodecahedron graincurved surfacestruncated edgescornersMinimum interface energy configurations of a uniformly intermixed grain-matrix aggregate are determined for various dihedral angles and matrix contents by numerical analysis of a ...
Herein, we report that the dihedral angle change in tritopic ligands with three 4-pyridyl rings attached to a central aromatic ring afforded different self-assemblies of M3nL2n(n = 3 and 4). Metal-complexation of tritopic ligand2withθaround 36° gave an M9L6open triaugmented triangular...
Let us consider the self-assembly of Pd2+ and tritopic ligand 2 (Fig. 1b), whose structure is basically the same as 1 except for the dihedral angle (θ) between the 4-pyridyl rings and the central ring (θ for 1 is 0°, while θ for 2 is larger than 0°). Because the ...