doi:10.1016/S0040-4020(00)00725-0Mohamed SalimAlfredo CaprettaElsevier BVTetrahedronM. Salim, A. Capretta, "Intramolecular Carbenoid Insertions: the Reactions of a- Diazoketones Derived from Pyrrolyl and Indolyl Carboxylic Acids with Rhodium(II) Acetate" Tetrahedron, 2002, 56, 8063-8069....
ChemInform Abstract: Diastereoselective Intermolecular OH Insertions by Cu(II)-Mediated Carbenoids Derived from Phenyldiazoacetamidealcohols (benzene compounds)diastereoselective syntheses, enantioselective syntheses (incl. ci/trans-isomerism)ChemInform is a weekly Abstracting Service, delivering concise information...
carbenoidsα-aryl-α-diazo-ketonesrhodiumIn a further contribution to the fieldof donor/acceptor metal carbenoids, the presentpaper discusses the enantioselective intermolecu-lar reactions of rhodium carbenoids derived froma-aryl-a-diazoketones. Reaction with activated olefins generates cyclopropyl ketones...
J. Moody.Synthetic applications of the O-H insertion reactions of carbenes and carbenoids derived from diazocarbonyl and related diazo compounds.Tetrahedron. 1995D. J. Miller,,C. J. Moody.Synthetic applications of the O-H insertion reactions of carbenes and carbenoids derived from diazocarbonyl ...
Cuevas-Yanez et al., " Rhodium(II) catalyzed intramolecular insertion of carbenoids derived from 2-pyrrolyl and 3-indolyl .alpha.-diazo-.beta.-ketoesters and .alpha.-diazoketones ", Tetrahedron 2004, 60(7), 1505-1511.E. Cuevas-Yane,J.M. Muchowski,R. Cruz-Almanza.Rhodium (Ⅱ) ...
Cuevas-Yanez et al., " Rhodium(II) catalyzed intramolecular insertion of carbenoids derived from 2-pyrrolyl and 3-indolyl .alpha.-diazo-.beta.-ketoesters and .alpha.-diazoketones ", Tetrahedron 2004, 60(7), 1505-1511.E. Cuevas-Yane,J.M. Muchowski,R. Cruz-Almanza.Rhodium (Ⅱ) ...
pyrrolidinesrhodium carbenoidN-H insertionThe rhodium acetate catalyzed reaction of D-glucose-derived δ-amino α-diazo β-ketoester allows a stereoselective β-facial intramolecular N-H insertion reaction that leads to formation of the bicyclic pyrrolidinone ring skeleton in high yield. The sugar-sub...
Rhodium (Ⅱ) catalyzed intramolecular insertion of carbenoids derived from 2-pyrrolyl and 3-indolyl a-diazo-b-ketoesters and a-diazoketones. E. Cuevas-Yane,J.M. Muchowski,R. Cruz-Almanza. Tetrahedron . 2004Cuevas-Yañez et al., " Rhodium(II) catalyzed intramolecular insertion of carbenoid...
Remarkable substituent effects on the chemoselectivity of rhodium(II) carbenoids derived from N-(2-diazo-3-oxobutyryl)-L-phenylalanine esters. Zaragoza F. Tetrahedron . 1995Florencio Zaragoza, remarkable substituent effects on the chemoselectivity of rhodium(II) carbenoids, Tetrahedron, 51(32), 8829...
carbenoidsmonosaccharidesReactions of 6-O-protected diazo derivatives 8, 9 and 10 with transition metals Rh(II) and Cu(II) under a variety of different conditions of solvents and temperatures, were studied in order to obtain 2-C-alkyl analogues of KDO. In fact, these types of products (11...