The synthesis of a new 1,1-dithiolate ligand, 1,3-dithiepin-2-carbodithiolate (L2−), has been accomplished from the reaction of carbon disulfide with the lithium salt of 1,3-dithiepin. Copper(II) and palladium(II) complexes of the formula ML22− were isolated as the ...
Compared to the disulfide bonds, the bonding energy of a diselenide bond is lower (diselenide bonds: 172 kJ mol−1; disulfide bonds: 240 kJ mol−1), so the diselenide bonds are more labile to be dynamically broken and reconstructed than disulfide bonds45. So far, ...
If substituents are on thesame side of the double bondof the dienophile they will be on thesame side of the product ring. If substituents are onopposite sides of the double bondof the dienophile they will be onopposite sides of the product ring. ...
5-Ethylthio-1H-Tetrazole(ETT) 15088-78-5 079 Phenylacetyl Disulfide(PADS) 1075198-30-9 783 (1-Cyano-2-ethoxy-2-oxoethylidenaminooxy)dimethylamino-morpholino-carbenium hexafluorophosphate 153433-21-7 651 pyoxime 21871-47-6 104 5-Benzylthio-1H-tetrazole (BTT) 1122-28-7 301 4...
DIISOAMYL DISULFIDE 二异戊基二硫醚 2051-04-9 Pindolol 吲哚洛尔 13523-86-9 5-Fluoro-2-methylindan-1-one 2-甲基-5-氟茚满酮 41201-58-5 ISOTHIPENDYL 氮异丙嗪 482-15-5 Miloxacin 米洛沙星 37065-29-5 Quinbolone Quinbolone 2487-63-0 Renzapride 伦扎必利 112727-80-7 Dalfopris...
Methyl3-methyl-2-nitrobenzoate 5471-82-9 1,1-Diphenyl-bistetrazole-5,5-disulfide 5117-07-7 3,5-Dinitro-2-toluicacid 28169-46-2 Tungsten(VI)chloride 13283-01-7 4-Aminophenol 123-30-8 Colorpaste(blue) ChlorinatedParaffin 63449-39-8 nickelsulfate,hexahydrate 10101-97-0 Methylethy...
Chlorine on pyrazine, tetrazole, thiazole, as in the example of equation (13), and quinoline rings, was sufficiently reactive to produce a clean substitution. It was proposed that the reaction proceeds via SNAr displacement of the suitably activated leaving groups (halide and also nitrite) by N...
tetrazole. In other preferred embodiments the support-bound phosphite is oxidized with a sulfurization reagent such as Beaucage reagent, tetraethylthiuram disulfide, dibenzoyl tetrasulfide, phenacetyl disulfide, 1,2,4-dithiuazoline-5-one, 3-ethoxy-1,2,4-dithiuazoline-5-one, a disulfide of a ...
(1) M.F. worked on the topic as her MSc. Thesis and prepared the initial draft of the manuscript. (2) M.R.N.-J. is the first supervisor of Miss Fathi and Dr. Leila Panahi as his MSc. and postdoc researcher, respectively. Also, he edited the manuscript completely. (3) M.G.D...