ChemInform Abstract: Efficient H—D Exchange Reactions Using Heterogeneous Platinum-Group Metal on Carbon—H2—D2O Systemdoi:10.1002/chin.201225254organic chemistry, reviewlabeling reactions, deuterationReview: ca. 100 refs.Yoshinari SawamaLab. Org. Chem., Gifu Pharm. Univ., Gifu 501-11, Japan...
Energetics and dynamics of proton transfer reactions along short water wires. Proton transfer (pT) reactions in biochemical processes are often mediated by chains of hydrogen-bonded water molecules. We use hybrid density functional c... RI Ville,Kaila,Gerhard,... - 《Physical Chemistry Chemical Phy...
Efficient H-D Exchange Reactions Using Heterogeneous Platinum-Group Metal on Carbon-H2-D2O Systemorganic chemistry, reviewlabeling reactions, deuterationReview: ca. 100 refs.doi:10.1002/chin.201225254Yoshinari SawamaYasunari MonguchiHironao Sajiki
- 《European Journal of Organic Chemistry》 被引量: 0发表: 2024年 Half-sandwich Complexes of Ruthenium; Synthesis and Application to Catalysis Moreover, the H/D exchange reactions of polar substrates were also observed in D2O, which is the most attractive deuterium source due to its low cost ...
- 《Journal of Physical Chemistry A》 被引量: 205发表: 1999年 Stereochemistry and mechanism of reactions catalyzed by tryptophanase Escherichia coli. Several beta replacement and alpha,beta elimination reactions catalyzed by tryptophanase from Escherichia coli are shown to proceed stereospecifically with....
To understand the substituting group effects of organic ligands on the reaction equilibrium, the interactions between diperoxovanadate complex [OV(O2)2(D2O... Xianyong,Yu,and,... - 《Spectrochimica Acta Part A Molecular & Biomolecular Spectroscopy》 被引量: 21发表: 2008年 NMR and theoretical ...
Adding a few drops of D2O to an NMR sample containing acidic protons causes them to be replaced by deuterium. A possible mechanism is shown above. The vast number of water molecules in one drop of D2O drives the equilibrium so that the ethanol OH is completely replaced by deuterium. ...
In addition, D2O is often adopted to confirm the hydrogenation mechanism in electrocatalytic hydrogenation reactions. We thus propose that the combination of α-H/D exchange and electrocatalytic C ≡ N deuteration of aryl acetonitriles will be highly promising for achieving a one-pot ...
- 《Dalton Transactions An International Journal of Inorganic Chemistry》 被引量: 3发表: 2011年 Mechanisms for acceleration of halide anation reactions of platinum(IV) complexes. REOA versus ligand assistance and platinum(II) catalysis Without central... Chloride anation of trans-Pt(CN)4ClOH2−...
phosphanylnaphtho[2,1-d]oxazoles, which could be applied as an efficient P,N-ligand in transition-metal-catalyzed C–N and C–C formation to produce the desired products in high yields with wide functional group tolerance under small catalyst loading, solvent-free conditions in many reactions....