glycosidic linkagesimulationPolysaccharides derived from D-glucopyranoside units are called glucans. They feature diverse glycosidic linkage patterns, mostly 1-3, 1-4 and/or 1-6 typesPeesapati, SruthiRoy, DurbaSocial Science Electronic Publishing
Starch is a carbohydrate reserve in plants and a major source of energy for humans. In plants, starch is found in chloroplasts of leaf and in the amyloplasts of tuber and seeds. Structurally, starch consists of two major polysaccharides, namely amylose and amylopectin. Both consists of chains...
InChIInChI=1S/C13H16O6/c14-9-10(15)12(16)18-8-6-17-13(19-11(8)9)7-4-2-1-3-5-7/h1-5,8-16H,6H2/t8-,9-,10-,11-,12?,13?/m1/s1 SMILESC1C2C(C(C(C(O2)O)O)O)OC(O1)C3=CC=CC=C3 Synonyms4,6-O-(Phenylmethylene)-D-glucopyranose; 4,6-O-Benzylidene-glucopyranose;...
47 Furthermore, the secondary structure of some mono-, oligo-, and polysaccharides has been investigated by vibrational Raman optical activity (VROA) spectroscopy.48, 49 Recently, a vibrational circular dichroism (VCD) study of discrimination of the glycosidic linkage position and stereochemistry (α...
Alpha-D-Glucopyranose pentabenzoate, also known as PGB, is a derivative of alpha-D-glucose that has significant potential in various fields of research and industry. This paper aims to provide a comprehensive overview of PGB, its physical and chemical properties, synthesis, characterization, analytic...
An examination of 13C- and 1H-chemical shifts in relation to the conformational stabilities of D-glucopyranose disaccharides and polysaccharidesVarious nmr spectroscopic techniques have been used to determine the orientation of the anomeric hydroxyl group of 2,3:5,6-di-O-isopropylidene-α-D-manno...
These are spacer-containing fragments of the capsular polysaccharides of Streptococcus pneumoniae type 2, 7F, 22F, and 23F, respectively, which are constituents of Pneumovax© 23. 2,3,4-Tri-O-benzyl-α-L-rhamnopyranosyl bromide was coupled to l,6-anhydro-2,3-di-(O-benzyl-β-D-...