theory can account satisfactorily for the difference in fall-off behaviour between the - and -1-propene yields, it cannot account for the pressure dependence of the formation of 2- and 3-fluoropropene; the latter behaviour is, however, easily understood in terms of the master-equation approach...
Based on the measured (cyclic voltammetry, CV) oxidation potential, using the Weller equation, electron transfer (ET) was predicted to occur. It was shown that the measured oxidation potential of represents the adiabatic ionization potential. For PET processes the value for the vertical ionization ...