38 Temperatures greater than 56°C led to increased amounts of 1-formyl-1-phenylthiocyclohexane (38). As an alternative to the Lewis acid conditions, it was found that sec-butyllithium (2 equiv.) also effected the transformation (55% yield).39 The dianion that is formed in this cas...
1. Chemical Name: Cyclohexanone diethyl ketal 2. CAS Registry Number: 1670-47-9 3. Synonyms: Cyclohexane, 1,1-diethoxy-; 1,1-Diethoxycyclohexane; Rum Acetal; 1, 1 - ジアルコキシ (C = 1–2) シクロヘキサン; シクロヘキサノンジアルキル (C = 2–5) ケタール; Cyclohexanone die...
Cyclohexanone -grown cultures grew readily on cyclohexanol, cis , trans -cyclohexane-1,2-diol, cis -cyclohexane-1,2-diol, ad... JR Murray,TA Scheikowski,IC Macrae - 《Antonie Van Leeuwenhoek》 被引量: 16发表: 1974年 Selective Oxidation of Cyclohexanone to Adipic Acid Using Molecular Oxygen ...
Resting cell suspensions of cyclohexanone-grown cells were found to oxidize cyclohexanone, cyclohexanol, cyclohexane-1,2-dione, cis , trans -cyclohexane-1,2-diol and 2-hydroxycyclohexane-1-one at high \\\({ext{Q}}_{{ext{O}}_{ext{2}} }\\\) values. Evidence was obtained that indicated ...
near to 100°C, in the presence of an acidic diatomaceous earth and dioxane. Thus, 2,6,6-trimethyl-1-(but-2-enoyl)-cyclohexan-3-one is prepared from either 2,6,6-trimethyl-2,3-epoxy-1-(but-2-enoyl)cyclohexan or 2,6,6-trimethyl-2,3-epoxy-1-(but-3-enoyl)-cyclohexane. ...
The route, I include a cyclohexane-1,2-diol dehydratase adipate semialdehyde dehydratase, and cyclohexane-1,2-diol dehydrogenase,. The route, 3-oxo-pin Moeller decarboxylase, 4-acetyl butyrate dehydratase, 3-hydroxy-cyclohexanone dehydrogenase, 2-cyclohexenone hydratase, cyclohexanone dehydrogenase, as ...
MRAZ J,GALOVA E,VITKOVA D.1, 2- and 1, 4cyclohexanediol: major urinary metabolites and biomarkers of exposure to cyclohexane, cyclohexanone, and cyclohexanol in humans. International Archives of Occupational and Envir . 1998Mraz J, Galova E, Nohova H, Vitkova D. 1,2- and 1,4-...