1) cyan,cyano-,nitrile group,nitrile grouping 氰基;腈基2) cyano benzyl cyanide 氰基苯乙腈3) isoamyl cyanide 异己腈;异戊基氰4) 2-aminoethyl-bi(2-nitrilethyl)amine 二(2-氰基乙基)氨基乙腈5) 1-Cyanocyclohexane acetonitrile 1-氰基环己基乙腈...
Nitrile as activating group in the asymmetric bioreduction of -cyanoacrylic acids catalyzed by ene-reductases. Adv Synth Catal, 2014, 356: 1878-1882Nitrile as Activating Group in the Asymmetric Bioreduction of β‐Cyanoacrylic Acids Catalyzed by Ene‐Reductases[J] . Christoph K. Winkler,...
is that cyano is a univalent functional group, -CN, consisting of a carbon and a nitrogen atom joined with a triple bond; organic compounds containing a cyano group are nitriles while cyanol is any of several blue dyes. cyano English Noun (en noun) (chemistry, especially in combinati...
Second, considering the nitrile group to be a weak H-acceptor, it is reasonable that sufficient H-bonding can only occur to stronger H-donors42. Incidentally, electron-poor alcohols not only increased donoring ability of the proton, but also decreased nucleophilicity on the oxygen atom43. ...
A Pd(OAc)2-catalyzed ortho-alkoxylation of arylnitrile was described. Using cyano as a directing group, the aromatic C–H bond can be functionalized efficiently to generate ortho-alkoxylated arylnitrile derivatives with moderate yields. The optimal reaction conditions were identified after examining ...
The Polymer Ionics Research Group has previously shown that the electron-withdrawing cyano substituents, incorporated in highly delocalized electron system, reduce the basicity of the anion; inhibiting electron donation toward alkali metal cations29. Moreover, introducing additional cyano substituents ...
Pd (OAc)2-Catalyzed Alkoxylation of Arylnitriles via sp2 C-H Bond Activation Using Cyano as the Directing Group. Li, W,Sun, P. Journal of Organic Chemistry . 2012Li W,,Sun P.Pd (OAc)2-Catalyzed Alkoxylation of Arylnitriles via sp2 C-H Bond Activation Using Cyano as the Directing ...
(DFT) and Monte Carlo simulations were applied to investigate the distinction of the anticorrosive behavior among the studied xanthenes toward the Al (111) surface. The non-planarity of xanthenes and the presence of the nitrile group were the key players in the adsorption process. A match ...
The 1,2,2-tricyanovinyl group (TCNV) accommodates three CN groups. From the point of view of the original acidity center, all CN groups are further away; therefore, inductively, they have a lower influence on the acidity. However, the resonance possibility creates additional acidity centers ...
The main products of hydrogen cyanide reproduction using sodium cyanide are: methyl methacrylate, butyl methacrylate, methacrylic acid, azobisisobutyronitrile, azobisisoheptonitrile, amino triacetic acid, hydroxyacetonitrile, etc. It is used in plastics, medicine, pesticides, dyes, metallurgy, ...