The layer displays a new and hitherto never observed H2O layer motif which may be described as L10(6). In 2 the Co2+ cation is surrounded by two bidentate amine molecules and a bidentate CO32− anion which was formed in situ by CO2 uptake from the atmosphere. N–H, O and Cl are ...
A new mixed-anion crystal composed of BEDT-TTF radical cation salt [BEDT-TTF]2(CuBr2)0.4(CuCl2)0.6 with an α'-type donor arrangement with a formal charge of +0.5 per BEDT-TTF was prepared by using a chemical oxidation method and characterized by using X-ray diffraction, four-probe ...
The trigonal environment of the Cu(I) atom in either complex anion includes is made up of two Cl atoms and the C≡C bond. Apart from the hydrogen bonds N-H⋯O that imparts a directed character to the ionic interaction Cat+⋯An−, the piperazinium cation with molecules of ...
Complex CationOxime GroupMonoterpenoidMenthaneThe synthesis of the [Cu(H 2 L)](NO 3 ) 2 complex ( I ) and of a mixed-valent complex [Cu(H 2 L)Cl] 2 [CuCl 2 ]Cl路0.5H 2 O ( II ), where L is chiral bis(menthane) propylenediaminodioxime. According to the data of single-...
The cation-anionic coordination compounds based on the copper(II) complexes with Phen and tartratogermanate anions, [Cu(Phen)(3)](2)[Ge-2(OH)(HTart)(mu-Tart)(2)] 11H(2)O (I) and [CuCl(Phen)(2)](4)[{Ge-2(OH)(2)(mu-Tart)(2)}Cl-2] 4H(2)? (II), with different ...
The trigonal environment of the Cu(I) atom in either complex anion includes is made up of two Cl atoms and the C≡C bond. Apart from the hydrogen bonds N-H⋯O that imparts a directed character to the ionic interaction Cat + ⋯An − , the piperazinium cation with molecules of ...
AbstractThe cation-anionic coordination compounds based on the copper(II) complexes with Phen and tartratogermanate anions, [Cu(Phen)3]2[Ge2(OH)(HTart)(-Tart)2]· 11H2O ( I ) and [CuCl(Phen)2]4[{Ge2(OH)2(-Tart)2}Cl2]· 4Н2О ( II ), with different compositions and ...