The results showed that [Cu(phen)(OAc)2]2( -H2O) exhibited high thermal stability and catalytic properties. Turnover number of dimethyl carbonate could reach to 33.0 molDMC molCu-1 under the conditions of reaction temperature of 120 , total pressure of 4.0 MPa, ratio of partial pr...
摘要: The[Cu_2(OAc)_4(Ur)(H_2O)](H_2O)_2 has been synthesized.The main infrared spectra absorption bands and thermostability of the complex has been assigned and studied.The possible structure of the complex has been also discussed....
The basal plane is occupied by two N atoms, one phenoxy O atom and one O atom from an OAc ligand, with an O atom of a bridging OAc ligand in the apical position. The apical Cu—O bond distance is longer than the equatorial Cu—N or Cu—O bond distances. In...
solid after keeping stirring in 24 h. Two clusters of [Cu25H22(PPh3)12]Cl and [Cu18H17(PPh3)10]Cl were isolated with a yield of 23% and 14%, respectively [40]. Following this study, the same group accomplished the synthesis of [Cu20(C≡CPh)12(OAc)6)] by the same approach [36...
region o f 2 2 0 —4 0 0 nm.C ry staJ struc ture determination Was c arried o ut on a B ruker SM A R T A P E X l 0 0 0 diffractometer. 2.2 Synthesis of compound Cu(phen)(m-C BA)2 Cu(OAc)2 H20 (0.1 997 g,1 mmo1),m—chlorobenzoic ...
Tell new mu -oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes described by the overall formula Cu(Br(4)Obbz)Ln(phen)(2)NO3 (Ln = Y, La,... YT Li,CW Yan,HD Wang - 《Polish Journal of Chemistry》 被引量: 19发表: 2000年 Synthesis and Crystal Structures of Three...
Copper ions play a vital role in a variety of fundamental physiological processes not only in human beings and plants, but also for extensive insects and microorganisms. In this paper, a novel water-soluble ruthenium(II) complex as a turn-on copper(II) i
配合物[Cd3(BTC)2(H2O)2]n 配合物[CuCl2(H2O)2][(Cbp)2]·H2O 配合物[Ni(tacn)2]2([Co(dmg)2Cl2]4(4H2O (C56H112Cl8Co4N28Ni2O20) [Cd(phen)2Cl2]·2H2O·EtOH 单核镉配合物[Cd(NTB)(η1-NO3)(SCN)(H2O)3 单核镉配合物[Cd(NTB)(η2-OAc)(N3)]·CH3OH·H2O ...
取代咪唑-Cu(Ⅰ)配合物对2-萘酚及其衍生物的催化氧化偶联 姓名:***申请学位级别:硕士 专业:有机化学 指导教师:**松 20040501 陈朋 四川人学硕1:学位论文 2004年 取代咪哩-cu(I)配合物对2-蔡酚及其衍生物的 催化氧化偶联 专业:有机化学 研究生: 陈丽...