It crystallizes in a monoclinic structure, space group C2/c with four formula units per unit cell. The general structural motif of ( 2), namely the formation of infinite Cu-pyrimidine chains, is retained. In contrast to ( 2), where the Cu ions are six-coordinate, dehydration leads to ...
The general formula of the complexes synthesised is [Ru(4,4'-(R-bpy)2(Cu(exoO2-cyclam))][NO3]2, where R = H, CO2Et and CO2H (Fig. 1). The ester analogue aids electronic characterisation of the system due to greater solubility, whereas the acid analogue was used for binding to ...
A similar observation has been reported by Bera et al.75, as they found the energy band gap of the Zn- s1nu.a6bn6so,tciatrnuytdsetda1l.ts7e.2tSr ieamVh,ielrdaerrsliypte,et(chCteiuvbe1a0lZyn,dnw2gSiatbhp4sSi1no3fc)rCneuaan1s2ioSncbgr4y−BxsiBtacilxosSn1in3tescn...
Tell new mu -oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes described by the overall formula Cu(Br(4)Obbz)Ln(phen)(2)NO3 (Ln = Y, La,... YT Li,CW Yan,HD Wang - 《Polish Journal of Chemistry》 被引量: 19发表: 2000年 Synthesis and Crystal Structures of Three...
Tell new mu -oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes described by the overall formula Cu(Br(4)Obbz)Ln(phen)(2)NO3 (Ln = Y, La,... YT Li,CW Yan,HD Wang - 《Polish Journal of Chemistry》 被引量: 19发表: 2000年 Calorimetric Studies on Antiferromagnetic a...
Syntheses, characterization and structures of heterodinuclear compound [CuIIL1BiIII(NO3)3] (1), sandwich type heterotrinuclear compound [(CuIIL1)2BaII(NO3)2]·0.2H2O (2), heterotetranuclear compound [{CuIIL1PbII(µ-NO3)(NO3)}2] (3) and... S Hazra,S Sasmal,M Nayak,... - 《Crys...
Effects of Zn(II), Cu(II), Mn(II), Fe(II), NO3−, or SO42− at pH 6.5 and 8.5 on transformations of hydrous ferric oxide (HFO) as evidenced by Mössb... The objective of the research is to determine the effects of transition metals on transformation of hydrous ferric oxide ...
(2-iminomethylene-6-methoxyphenol)) allowed the preparation of two families of heterotrimetallic complexes: three isostructural 1D coordination polymers of general formula {[CuII(valpn)LnIII(H2O)3(mu-NC)(2)Fe-III(phen)(CN)(2) {(mu-NC)Fe-III(phen)(CN)(3)}]NO3 center dot 7H(2)O}(...
X-ray study of structural domains in the near-surface region of SrTiO3 substrates with Y0.6Pr0.4Ba2Cu3O7/La2/3Ca1/3MnO3superlattices grown on top; ; Physical review. B, Condensed matter and materials physics; We investigated with synchrotron x-ray diffraction and reflectometry the formation of...
Cu (NO3)2·3H2O (1.05 g) was added to 30 mL (v/v, 1:1) water-ethanol mixture, followed by the addition of H3BTC (0.5 g). The solution was transferred into the lining of Poly Tetra Fluoro Ethylene (PTFE) and then sealed in the autoclave for reaction at 120 °C for 24 h. ...