[Cp((CO)2Fe(PPh2H)]PF6 reacts with NaBH4 to give the intermediates CpFe(CO)2H and PPh2H, which are then converted into Cp(CO)(H)Fe(PPh2H). [Cp(CO)2FeL]PF6 (L = P(OMe)3, P(OEt)3 and P(OiPr)3) reacts with NaBH4 to give the product Cp(CO)(H)FeL directly without Cp(...
The bimetallic carbocation complex [{Cp(CO) 2Fe} 2(μ-C 4H 7)]PF 6 reacted with trifluoroacetic acid to give the mononuclear cationic complex [Cp(CO) 2Fe{η 2-(CH 2CHCH 2CH 3)}]PF 6, which formed yellow orthorhombic crystals in the space group P2 12 12 1 with a = 7.652(4), ...