it seems that every time someone explains the color of ionic transition metals according to crystal field theory, the explanation involves ligands, as in ions or molecules that gave electron pairs to the d metal cation, rather than taking electrons from it in a redox reaction, so i'm at a ...
M.R. Churchill Transition metal complexes of azulene and related ligands Prog Inorg Chem, 11 (1970), pp. 53-98, 10.1002/9780470166123.ch2 Google Scholar [32] S. Töfke, U. Behrens Azulene as unusual η6-ligand and as η6:η4-Bridge in Mo-complexes Angew Chem Int Ed Engl, 26 (198...
The fluorescence enhancement effect of In3+ on metal complexes has not been previously reported, neither for transition metal nor lanthanide ions. The linear quenching behavior of Fe3+ functions in the 50–700 μM concentration range, and the linear enhancement behavior of In3+ is...
After a long hiatus, interest in boryl transition metal complexes has recently revived. This is principally due to their importance as intermediates in hydroborations catalyzed by metal complexes. It has been suggested that boryl gr...
Platinum metal pyridine complexes with light sensitive and solvent color transition effectdoi:CN101054395 AThe invention relates to a platinum metal pyridine complex with photosensitivity and solvent color distortion effect. The complex 2-methyl benzyldithiol 3- ethinyl-2,2-dipyridinyl platium is ...
metal complexes undergo such a type of solid single-crystal-to-single-crystal (SC-to-SC) transitions that are reversibly deformed. The original and transformed phases of the martensitic transition exhibit close orientation correlation and similar molecular packing within their crystal structures6,7,8,...
Syntheses and characterization of transition metal(Ⅱ) complexes of Schiff base derived from adamantaneamine and salicylaldehyde; 金刚烷胺水杨醛Schiff碱过渡金属(Ⅱ)配合物的合成与表征 2. Application and Synthesis of Salicylaldehyde; 水杨醛的应用及合成方法 3. Studies on the Synthesis,Structures and ...
Nonconventional or nonconjugated luminophore without polycyclic aromatics or extended π-conjugation is a rising star in the area of luminescent materials. However, continuously tuning the emission color within a broad visible region via rational molecul
Recently, advanced ab initio calculations of single nickel-related NE4 (nickel-vacancy) and NE8 (nickel-vacancy-nitrogen) complexes in nanodiamond provided an insight into the nature of optical transitions and demonstrated their potential for in vivo biomarker applications. For other transition metal-...
L. Tobe, “Base Hydrolysis of Transition-Metal Complexes”, Adv. Inorq. Bioinorq. Mech., (1983), 2, pages 1-94. The most preferred cobalt catalyst useful herein are cobalt pentaamine acetate salts having the formula [Co(NH3)5OAc]Ty, wherein “OAc” represents an acetate moiety and ...