Cation and anion vacanciesLaser irradiationWater splittingTOTAL-ENERGY CALCULATIONSCOBALT OXIDEEFFICIENTNANOPARTICLESPERFORMANCECRYSTALAtomic vacancy has been demonstrated to generate new energy states in the bandgap whereby providing more active sites in many electrocatalytic processes. In this work, a novel ...
Existence of the novel Cd2I62– anion and of the five-co-ordinate {Cd[N(CH2CH2NMe2)3]I}+ cation in Cd2[N(CH2CH2NMe2)3]I4 喜欢 0 阅读量: 11 作者:P.,L.,Orioli,M.,Ciampolini 摘要: X-Ray analysis of Cd2(tda)I4 shows the presence of a five-co-ordinate [Cd(tda)I]+...
Synthesis and characterisation of Co–Mo complexes containing the [Co(C 2 H 8 N 2 ) 3 ] 2+ cation and [Mo 2 O 7 L] 4 anion, where L is an oxalic, tartaric,... Synthesis and characterisation of Co-Mo complexes containing the [Co(C2HsN2)3]2: cation and [Mo207L/-anion, where...
Answer to: For Na2CO3, give the cation name and charge, anion name and charge, and name of the molecule. By signing up, you'll get thousands of...
The X-ray structure of the [N(PPh3)2]+(PPN)salt of [Ir4(CO)11(SCN)] shows that the anion possesses the C3ν-like arrangement of CO ligands with three bridging COs around a triangular face, and with the SCN ligand occupying an axial site on that face. This contrasts with the prev...
For LaCoODA, the activation will occur with the oxidation of the cobalt(II) centres through a single electron transfer to molecular oxygen and the formation of the superoxide anion [35]. In the case of LaCuODA, we recently reported the generation of a Cu−O2 adduct at the beginning of ...
The co-doping of Fe and PO4 constructs a stable oxygen-packed framework, which can alleviate lattice distortion, reduce the mixing of cations and increase the reversible reaction of 2O/(O2), contributing to outstanding structural stability. The synergetic strategy of anion and cation and the co...
Synthesis, structural characterization and biological activity of polyoxometallate-containing protonated amantadine as a cation A novel isopolyoxomolybdate complex (C10H18N)4Mo8O26·6(CH3)2SO 1 was synthesized, purified and characterized by means of elemental analysis, IR and 1H NMR... Juan,Li,...
248 2. The tetrahedron PO4 is in-cluded in an anion cage which is formed via condensed vanadium oxygen square pyramids(VO,) and octa-hedral(VO6) connected by As2O5 units through sharing oxygen atoms. The two Co cation is coordinatedby three en respectively, in which the six N atoms ...
Calculations at the MP4(SDQ) and CCSD(T) levels were also carried out for calibration. The calculations reveal the key role of non-covalent anion-solvent interactions, which modulate the anion-cation interaction ultimately altering the energetic balance between the two isomeric forms. 展开 ...