相关工作以“Experimental evidence of distinct sites for CO2-to-CO and CO conversion on Cu in theelectrochemicalCO2 reduction reaction”为题发表在Nature Catalysis上。 关键创新: 1、13CO/12CO2混合物作为反应性研究的进料,以确定产物的碳源,而通过原位表面增强红外吸收光谱(SEIRAS)探测到吸附的12CO和13CO的...
近日,华东理工大学戴升、台湾中央大学王冠文、台湾师范大学王祯翰等人在Nano Letters上发表了题为“Probing the Roles of Indium Oxides on Cooper Catalysts for Enhanced Selectivity during CO2-to-CO Electrochemical Reduction”的研究论文,利用原位X射线吸收光谱探索了Cu-In2O3复合催化剂在CO2还原过程中的结构演化与...
关于工程设计高性能催化剂,应更加注意催化剂的稳定性。催化剂的降解,CO中毒,形态转变和电解质污染将导致催化剂失活。 Song Jin et al. Advances and Challenges for Electrochemical Reduction of CO2to CO: From Fundamental to Industrialization. Angew., 2021...
The CO2reduction reaction is conducted and described in the Methods section to evaluate the catalytic activity of LaNi-Phen/COF-5 under simulated solar irradiation. The CO2RR performance of LaNi-Phen/COF-5 with various La-Ni metal proportions is monitored and optimized systematically (Supplementary T...
Selective and Efficient Photocatalytic CO2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst 来自 ACS 喜欢 0 阅读量: 230 作者:J Bonin,M Robert,M Routier 摘要: Converting CO2 into valuable compounds using sunlight as the energy input and an earth-abundant metal complex ...
to-CO. Cu is a potential catalyst to achieve CO2reduction to CO at the industrial scale, but the C-C coupling process on Cu significantly depletes CO* intermediates, thus limiting the CO evolution rate and producing many hydrocarbon and oxygenate mixtures. Herein, we tune the CO selectivity ...
值得注意的是,In-N3-V 位点表现出比 In-N4 位点更高的内在 CO2-to-CO 活性。DFT 计算表明,In-N3-V 结构产生更高能量的 In电子态(主要是 s 和 pz 轨道),有利于稳定 COOH* 中间体并促进 CO 的产生。与此同时,In-N3-V以及In-N4位点催化CO2到甲酸的能垒更高,从而抑制甲酸盐的产生。性能测试表明In-...
近日,我院王野教授和谢顺吉教授研究团队应邀撰写的综述性论文“Electrocatalytic reduction of CO2 and CO to multi-carbon compounds over Cu-based catalysts”发表于Chemical Society Reviews (DOI: 10.1039/ D1CS00535A)。论文系统评述了铜基催化剂上...
Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO2 Reduction to CO We develop a model based on density functional theory calculations to describe trends in catalytic activity for CO2 electroreduction to CO in terms of the ... HA Hansen,JB Varley,AA Peterson,.....
project, expecting to generate additional income for the project with an annual emissionreductionof41,160 tonsofCO daccess-ods.un.org daccess-ods.un.org 在德里地铁项目中,该项目被注册为 一个清洁发展机制项目,预计能够通过每年减少排放41 160 吨二氧化碳为该项 目带来额外收入。