CO2 reductionSingle atom catalystAsymmetrical active sitesC2 productionDensity functional theoryElectrochemical reduction of CO2 requires catalysts beyond Cu with high activity and selectivity to produce C2 products. Different from many single-atom catalysts that show high performance in obtaining C1 products,...
Xuanyu Feng et al. Metal-Organic Frameworks Significantly Enhance Photocatalytic Hydrogen Evolution and CO2 Reduction with Earth-Abundant Copper Photosensitizers.Journal of the American Chemical Society,2020, DOI:10.1021/jacs.9b12229. 3、Journal of the American Chemical Society:调整局部CO2的利用率实现高效...
Promoting Electrocatalytic CO2 Reduction to CH4 by Copper Porphyrin with Donor–Acceptor Structures. Small, 2022. DOI: 10.1002/smll.202205730清新电源投稿通道(Scan)阅读原文微信扫一扫关注该公众号 人划线
该催化剂在CO2电还原制乙醇中,表现出色的性能,并且研究人员通过实验结合理论对催化机理进行深入研究。该工作以“Highly selective electrocatalytic CO2reduction to ethanol by metallic clusters dynamically formed from atomically dispersed ...
Xinyan Liu, Albert K. Engstfeld, Sebastian Horch, Brian Seger, Ifan E. L. Stephens, Karen Chan, Christopher Hahn, Jens K. Nørskov, Thomas F. Jaramillo, Ib Chorkendorff, Progress and Perspectives of Electrochemical CO2Reduction on Copper in Aqueous Electrolyte. Chem. Rev., 2019, 119, 761...
Mao, X., He, T., Kour, G., Yin, H., Ling, C., Gao, G., ... & Du, A. (2024). Computational Electrocatalysis beyond Conventional Hydrogen Electrode Model: CO2 Reduction to C2 Species on Copper Facilitated by Dynamically Formed Solvent Halide Ions at the Solid-Liquid Interface. ...
图2.原位在线ICP-MS测量阴极偏压下铜纳米颗粒的溶解速率 参考文献: Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction, Nat. Catal., 2024. DOI: 10.1038/s41929-023-01070-8 https://doi.org/10.1038/s41929-023-01070-8...
& Han, Z. Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore. Nat. Commun. 12, 1835 (2021). Article ADS Google Scholar Rao, H., Schmidt, L. C., Bonin, J. & Robert, M. Visible-light-driven methane formation from CO2 with a molecular iron catalyst. ...
近日,北京理工大学陈文星副研究员和河北科技大学王硕副教授合作,在国际知名期刊ACS Energy Letters上发表题为“Factors Influencing the Performance of Copper-Bearing Catalysts in the CO2Reduction System”的综述文章。该综述文章分析了影响体相催化剂、含铜化合物催化剂、合金催化剂和单原子催化剂四个体系的含铜催化剂...
综上所述，本研究为制备高金属负载的单原子催化剂提供了一条新途径，所制备的高效、稳定的催化剂在电催化CO2RR制乙醇方面具有很大的应用潜力。Adjacent Copper Single Atoms Promote C–C Coupling in Electrochemical CO2 Reduction for the Efficient Conversion of Ethanol, Journal of the American Chemical Society,...