5. *CHO基本上不参与C2+途径。 上述反应机理为构筑高效催化C2+产物生成的CO2RR催化剂提供了理论依据,并为CO2RR电催化剂的设计提供了清晰的指导原则。 文献信息 Time-resolvedobservation of C-C coupling intermediates on Cu electrodes for selectiveelect...
在串联催化电极中,各组分布置良好,且各自的功能得到充分利用。 Hierarchical tandem catalysis Promotes CO spillover and trapping for efficient CO2 reduction to C2+ products.ACS Nano, 2025. DOI: 10.1021/acsnano.5c00696 电池 催化 理论计算 华算科技 顶刊...
A. (2024). Computational Electrocatalysis beyond Conventional Hydrogen Electrode Model: CO2 Reduction to C2 Species on Copper Facilitated by Dynamically Formed Solvent Halide Ions at the Solid-Liquid Interface. Chemical Science.https://doi.org/10.1039/D3SC06471A ...
这项工作表明,通过在晶格中掺入二次阳离子来调节氧化铜可以进一步提高配位不饱和和高价态Cu位点的稳定性,从而提高ECO2RR性能。 Stabilization of Undercoordinated Cu Sites in Strontium Copper Oxides for Enhanced Formation of C2+ Products in Electrochemical CO2 Reduction. ACS Catalysis, 2022. DOI: 10.1021/acs...
这项工作首次尝试了通过严格控制Cu NWs的氧化,以证明Cu催化剂对CO2RR的活性,选择性和稳定性方面的重要性。相关工作以”Controlling the surface oxidation of Cu nanowires improves their catalytic selectivity and stability toward C2+p...
相关工作以“Steering the Dynamics of Reaction Intermediates and Catalyst Surface during Electrochemical Pulsed CO2Reduction for Enhanced C2+Selectivity”为题发表在国际著名期刊Journal of the American Chemical Society上。 研究要点 要点1. 作者使用多晶铜箔作为模型系统,重点研究了CO2RR中反应中间体的脉冲诱导动力...
模拟Cu基金属-有机框架酶还原CO2成C2产物的计算设计与实验验证:配体调制促进的C-C偶联和最佳Cu-Cu距离 Computational Design and Experimental Validation of Enzyme Mimicking Cu-Based Metal–Organic Frameworks for the Reduction of CO2 into C2 Products: C–C Coupling Promoted by Ligand Modulation and the Opt...
Herein, using density functional theory (DFT), the electrocatalytic CO2 reduction reaction (CRR) was applied towards making C1 products (CO, HCOOH, CH3OH, HCHO, and CH4) on monolayer C2N frameworks with M3 (M = Fe, Co, Ni, Cu) metal clusters introduction. Analyses of the adsorption ...
图5. 阳离子-水-吸附物模型 文献信息 Yang, X., Ding, H., Li, S., Zheng, S., Li, J. F., & Pan, F. (2024). Cation-Induced Interfacial Hydrophobic Microenvironment Promotes the C–C Coupling in Electrochemical CO2 Reduction. Journal of the American Chemical Society.
该研究表明利用聚合物粘合剂调节电催化剂的疏水性是调节气-固-液界面电化学反应性能的一种很有前途的方法。 Enhanced Electrocatalytic CO2Reduction to C2+Products by Adjusting the Local Reaction Environment with Polymer Binders., DOI: 10.1002/aenm.202103663. https://doi.org/10.1002/aenm.202103663....