Molecular geometry of M(NO)2 complexes: single crystal X-ray structure of Co(NO)2(C5H5N)2+BF4−, lability of the pyridine ligands of Co(NO)2(C5H5N)2+, and its relevance to the formation of the Co2(NO)3+ bimetallic core Share PREVIOUS ARTICLE Integral method for infinite dilution act...
MICHAEL B. SMITHROBERT D. WILSONROBERT BAUWILEY‐VCH Verlag GmbHChemischer InformationsdienstChin, H., Smith, M.B., Wilson, R.D. and Bau, R. (1974) Variations in molecular geometry along the isoelectronic series [Co 2 (CO) 8 ], [FeCo(CO) 5 ] and [Fe 2 (CO) 8 ] 2- . J. ...
Freeze-drying, the full name is vacuum freeze drying. Freeze-drying consists of two main steps: (1) the material containing a large amount of water is cooled down in advance and frozen into a solid below the freezing point; (2) the ice is sublimated directly under vacuum conditions, thus ...
The solvation effect was taken into account by using an implicit solvation model70,71as implemented by the Hening group under the name VASPsol72, where a dielectric constant of 78.4 corresponds to solvent water. In addition, in the cases where there are strong interactions between the adsorbate ...
Liquids are generally deemed non-porous fluid, albeit the presence of ill-defined shapes and spaces indeed occur due to the random molecular motion [1]. The introduction of new liquid molecules that exhibits permanent porosity while maintaining their fluidity properties, termed as ‘porous liquid’ ...
3.2.1. Molecular Level (0) → Pore Level (I) At Level I, the poro-elastic stress-strain response is that of a porous material with porosity 𝜑. The poro-elastic constitutive response is given by: 𝛔=ℂ𝐼:𝛆−𝒃𝐼𝑝 (1) 𝜑−𝜑0=𝒃𝐼:𝛆+𝑝𝐼𝑁𝐼 ...
which depended on the amine concentration. The optimal combination of these parameters was found for the PUR/TEPA membrane (5 wt.% of TEPA in spinning solution): the sorption capacity was 13.97 cm3/g with an air permeability of 0.020 m/s. Molecular modeling proved to be a valuable tool ...
Its name derives from the fact that CO2 replaces steam in the conventional steam methane reforming process (Hartley & Tam, 2012). This reaction can be represented as P−−S−PS−−−−SY−−=0–P_S−PS__SY_=0_E15 According to Hartley and Tam (2012), dry ...
CationAnionName of Ionic liquidAbbreviationPurity (Mass Fraction) EthylenediammoniumButanoate [ED][But] >0.97 EthylenediammoniumPentanoate [ED][Pent] >0.97 EthylenediammoniumHexanoate [ED] [Hex] >0.97 EthylenediammoniumHeptanoate [ED][Hep] >0.97 * All of the ionic liquids used for were produced in ...
Chemischer InformationsdienstChin, H., Smith, M.B., Wilson, R.D. and Bau, R. (1974) Variations in molecular geometry along the isoelectronic series [Co 2 (CO) 8 ], [FeCo(CO) 5 ] and [Fe 2 (CO) 8 ] 2- . J. Amer. Chem. Soc. , 96 5285–5287....