Oyola-Rivera, O., Baltanas, M.A., Cardona-Martinez, N., 2015. CO2 hydrogenation to methanol and dimethyl ether by Pd-Pd 2 Ga catalysts supported over Ga2O3 poly- morphs. J. CO2 Util. 9, 8-15.CO 2 hydrogenation to methanol and dimethyl ether by Pd–Pd 2 Ga catalysts supported ...
CO2 hydrogenation to methanol on tungsten-doped Cu/CeO2 catalysts The catalytic hydrogenation of CO 2 to methanol depends significantly on the structures of metal-oxide interfaces. We show that doping a high-valency metal... Y Yan,RJ Wong,Z Ma,... - 《Applied Catalysis B Environmental》 被...
根据文献报道,CO2转化甲醇通常是CO中间体路径和甲酸盐(*HCOOH, *H2COOH, *CH3O)中间体路径。而根据计算ZnCu(111)则优先选择甲酸盐路径,而由于纯Cu和CuZn位点不易与CO2的结合,所以此时CO2加氢通过Eley-Rideal(ER)机理进行反应生成甲醇。又由于Zn位点对氧的强亲和力CO2...
论文的第一作者为中国科学院上海高等研究院周紫璇和王雨晨,通讯作者为李圣刚研究员和高鹏研究员。详见:Zhou Z, Wang Y, Bao Y, Yang H, Li J, Chang C, Li S, Gao P. Nickel-modifiedIn2O3with inherent oxygen vacancies fo...
A promising approach for chemical energy storage from fluctuating renewable electricity is methanol synthesis from CO2 and hydrogen in a slurry reactor concept, due to efficient heat storage and easy reactor control. In combination with a promising In2O3/ZrO2 catalyst and mineral oil as carrier ...
CO2hydrogenation to methanol is very promising [[2], [3], [4]]. It can be applied for the conversion of carbon dioxide in a large scale. The product, methanol, can be extensively used as chemical intermediate, solvent, fuel, and others. A ‘Methanol economy’ was even proposed by Prof...
The role of ZnO–ZrO2interaction is an ongoing debate. Recently, it was reported that the binary ZnO–ZrO2oxide in the solid solution state also shows activity for CO2hydrogenation to methanol34. The Zn-doped ZrO2without the presence of Cu could achieve high CO2conversion (10%) and methanol ...
In 2 O 3 CO 2 Hydrogenation Methanol ABSTRACT ThesuperiorcatalyticactivityofIn 2 O 3 forCO 2 hydrogenationtomethanolisdemonstratedhere.The experimentalresultsdemonstratethatthereactiontemperatureandpressurehaveasignificant influenceonmethanolyield.TheconversionofCO 2 overIn 2 O 3 increaseswiththeincrease...
Reduction of CO2to methanol using renewable hydrogen is a promising but challenging strategy for carbon capture and utilization. Although methanol synthesis via CO hydrogenation has been industrialized, CO2hydrogenation to methanol still confronts great obstacles of low methanol selectivity and poor stability...
Modulation of Electronic Metal-Support Interaction between Cu and ZnO by Er for Effective Low-Temperature CO<inf>2</inf> Hydrogenation to Methanol 2024, ACS Catalysis A Derivative of ZnIn<inf>2</inf>S<inf>4</inf> Nanosheet Supported Pd Boosts Selective CO<inf>2</inf> Hydrogenation ...