王亮ACS Nano：酰胺共价键工程：显著增强光催化CO2还原活性 光催化CO2转化为增值产品是缓解能源危机和环境问题的有效手段之一。然而，目前大多数光催化剂低效的电荷分离效率和缓慢的界面反应动态学严重阻碍了光催化还原CO2的效率。根据文献报道，构建异质结构光催化剂通过建立合适的能带结构和调控电子传输途径，有效地促进了...
总之,II型电荷转移机制和酰胺键通道的耦合促进了光生载流子的有效迁移和分离,从而提高了CN-CQD的光催化性能。 Amide Covalent Bonding Engineering in Heterojunction for Efficient Solar-Driven CO2 Reduction. ACS Nano, 2023. DOI: 10.1021/acsnano.3c07411...
Solymosi F.The bonding, structure and reactions of CO2 adsorbed on clean and promoted metal surfaces.Journal of Molecular Catalysis. 1991Solymosi F.The Bonding, Structure and Reactions of CO2 Adsorbed on Clean and Promoted Metal Surfaces. Journal of Molecular Catalysis . 1991...
总之,II型电荷转移机制和酰胺键通道的耦合促进了光生载流子的有效迁移和分离,从而提高了CN-CQD的光催化性能。 Amide Covalent Bonding Engineering in Heterojunction for Efficient Solar-Driven CO2 Reduction. ACS Nano, 2023. DOI: 10.1021/acsnano.3c07411...
根据原位ATR-SEIRAS和DFT计算结果，*CO很容易从Mo2C/N-CNT表面脱附，不利于后续的转化。在生成*OCHO*后，还原得到H2C*O*OH中间体，进一步反应生成CH2O*和CH3OH。Selective CO2 electroreduction to methanol via enhanced oxygen bonding. Nat. Commun., 2022, DOI: 10.1038/s41467-022-35450-8.
Jingyi Lia, Xiang Lia, Charuni M. Gunathunge, and Matthias M. Waegele Hydrogen bonding steers the product selectivity of electrocatalytic CO reduction PNAS 2019 116 19 Charuni Menaka Gunathunge, Jingyi Li, Xiang Li, Julie J Hong, and Matthias M. Waegele Revealing the Predominant Surface ...
Comparison of rhodium-ethylene and rhodium-tetrafluoroethylene bonding The molecular and crystal structures of 蟺-cyclopentadienylethylenetetrafluoroethylenerhodium, (C5H5)Rh(C2F4)(C2H 4), have been determined from room-temperature X-ray diffractometer data. The molecule has idealized C8(m) symmetry with...
这项工作开辟了一条新途径,可以同时调节单原子催化剂的几何和电子结构以实现高效的 CO2 转化。相关文章以“Fe-N4O-C Nanoplates Covalently Bonding on Graphene for Efficient CO2 Electroreduction and Zn-CO2 Batteries”标题发表在Advanced Functional Materials。
Selective CO2 electroreduction to methanol via enhanced oxygen bonding. Nat. Commun., 2022, DOI: 10.1038/s41467-022-35450-8. 发布于 2023-12-28 09:43・IP 属地广东 化学 催化 天津大学 赞同添加评论 分享喜欢收藏申请转载 ...
and the other side of molecular bonding for b-CO2would consolidate a binding of CO* preferentially at the atop site on the Rh surface. At equilibrium, it is possible for dissociated O*, CO* and chemisorbed b-CO2to exist together at the same Rh terrace; meanwhile, the resolved peaks of ...