Increasing the amount of cobalt induces a change in the local symmetry of MgO 6 octahedra witnessed by the change of the metal-ligand bond distances.The changes are attributed to the larger ionic radius and electronegativity of Co 2+ ions compared to the Mg 2+ ions in the host lattice....
Unexpected insertion of CO2 into the pentacoordinate P–N bond:Atherton-Todd-type reaction of hydrospirophosphorane with amines. Cao SX,Gao P,Guo YC,Zhao HM,Wang J,Liu YF,Zhao YF. Journal of Organic Chemistry . 2013Cao SX,Gao P,Guo YC,Zhao HM,Wang J,Liu YF,Zhao YF.Unexpected ...
Reactions of CO2 and ethane enable CO bond insertion for production of C3 oxygenates Article Open access 20 April 2020 Data availability The experimental data relating to the figures and tables presented in this manuscript are available online in the Zenodo repository at https://doi.org/10.5281...
In situ Raman measurements revealed the presence of the intermediate *CO and C–H bond, while the ECOR experiments excluded *CO dimerization for C2H4 formation. By comparing the reaction energy of possible reaction intermediates (such as *CHO dimerization, *CO + *COH), the favourable C–C ...
[91] 91 Mizuno H, Takaya J, Iwasawa N. Rhodium(I)-catalyzed direct carboxylation of arenes with CO2 via chelation-assisted C-H bond activation. J Am Chem Soc, 2011, 133: 1251-1253 Full-Text Contact Us service@oalib.com QQ:3279437679 WhatsApp +8615387084133 ...
Unusual Intramolecular Hydrogen Bond in Lantern-Type Trimethylacetate Cobalt(II) Complexes: Synthesis and Structure of [C2H5CH(NO2)CH2CMe(=NOH)]2Co2(μ-OOC... Unusual Intramolecular Hydrogen Bond in Lantern-Type Trimethylacetate Cobalt(II) Complexes: Synthesis and Structure of [C2H5CH(NO2)CH2CMe...
and the change of gas and liquid Reynolds number scatter plot and the plot of Nusseltnumber change with Bond number, it can provide insight into the CO 2 tube flow boiling heat transfer characteristicsand the future research a new type of heat transfer correlations for more accurate to provide...
(carbon monoxide), CO2 (carbon dioxide), CH4 (methane), HCO (the formyl radical), H2CO (formaldehyde), CH3CH2OH (ethanol), HC((double bond)O)NH2 ... MP Bernstein,SA Sandford,LJ Allamandola,... - 《Astrophysical Journal》 被引量: 568发表: 1995年 The effects of clear-cutting on soil...
inthiswork.Thebond paths inthemolecular graphs of71;electron density andtotalelectrondensity showtheSal'ile orientation.indicating thatthe7【…7cinteractions play the important roleintheseintermolecular interactions. Key words:S…冗interactions,7【…冗interactions,intermolecularinteractions,兀electrondensity fun...
Reactions of CO2 and ethane enable CO bond insertion for production of C3 oxygenates Article Open access 20 April 2020 Selective conversion of CO2 to isobutane-enriched C4 alkanes over InZrOx-Beta composite catalyst Article Open access 06 May 2023 Data availability Data used to plot the figu...