The reaction of [RuHCl(CO)(PPh_3)_3] with pyrazine has been examined and a ruthenium(II) complex - [RuHCl(CO)(PPh_3)_2(C_4H_4N_2)] - has been obtained. The compound has been studied by IR, UV-Vis spectroscopy, and X-ray crystallography. The molecular orbital diagram of the ...
The orbital nature of the lowest (3)MLCT manifold is fully corroborated by a molecular orbital diagram derived from quantum chemical modeling studies, while the existence of the localization, localized mixed valency, and second-order charge transfer rely on spectral evidence alone. This work makes ...
aSchematic diagram of the synthesis of CEAA dyes using a continuous flow microreactor.bFluorescence spectra of TPE, C-6, and LR305 in acetonitrile.cFluorescence spectra of TPE, C-6, and LR305 in water.dOptical photos of TPE, C-6@TPE, and LR305@TPE in water under 365 nm UV light....
a, Transcription factors search for targets in a local interaction hub by a bound-state-dominant mode. Local exploration is proposed to be guided by transient interactions with other co-regulators (proteins or non-coding RNAs) in the hub; TF, transcription factor.b, The diagram illustrates the ...
Figure 3. (a) The c-axis lattice parameter changes pf LiNi0.6Co0.4O2, LiNi0.6Co0.2Mn0.2O2 and LiNi0.6Mn0.4O2; (b) High magnification TEM image of LiNi0.6Co0.4O2 after cycling; (c) Density of states schematic diagram of TMs and O; (d) In-situ differential electrochemical mass spectrosco...
In subject area: Biochemistry, Genetics and Molecular Biology Water purification encompasses the removal of pollutants such as industrial dyes, heavy-metal ions, microplastics, and organic matter from water as well as the collection of freshwater (e.g., through seawater desalination or atmospheric cond...
aSchematic diagram of LDH nanosheet synthesis and the subsequent drug loading.bMechanism of antitumor immune responses against orthotopic lung tumors by TTA-Q6/RRX-001 co-delivery. (1) T-type calcium influx channel blockage by TTA-Q6, (2) calcium homeostatic deficiency in parallel with the CD47...
Schematic diagram of the synthesis of 1D Co9S8-V3S4/CC nanowires. 。 After sulfurization,the diffraction peaks of Co9S8-V3S4/CC can be well indexed to V3S4(PDF No.18-1456)and Co9S8(PDF No.02-1459)phases(Fig.2a).No other peaks of impurities can be found,indicating the decompositio...
The detailed schematic diagram of ESTEM can be found in Supplementary Fig. 20. It is generally known that Ni nanoparticles could be oxidized to form superficial NiO layers upon exposure to air at ambient conditions, which inevitably ruined original surface configurations of the reduced catalyst. In...
nism, CO oxidation on PN2C1-G is more favorable Scientific Reports | Vol:.(1234567890) (2022) 12:10439 | https://doi.org/10.1038/s41598-022-14286-8 6 www.nature.com/scientificreports/ Figure 5. The potential energy surface diagram of CO oxidation via the first step in an ER...