The reaction of [RuHCl(CO)(PPh_3)_3] with pyrazine has been examined and a ruthenium(II) complex - [RuHCl(CO)(PPh_3)_2(C_4H_4N_2)] - has been obtained. The compound has been studied by IR, UV-Vis spectroscopy, and X-ray crystallography. The molecular orbital diagram of the ...
The orbital nature of the lowest (3)MLCT manifold is fully corroborated by a molecular orbital diagram derived from quantum chemical modeling studies, while the existence of the localization, localized mixed valency, and second-order charge transfer rely on spectral evidence alone. This work makes ...
aSchematic diagram of the synthesis of CEAA dyes using a continuous flow microreactor.bFluorescence spectra of TPE, C-6, and LR305 in acetonitrile.cFluorescence spectra of TPE, C-6, and LR305 in water.dOptical photos of TPE, C-6@TPE, and LR305@TPE in water under 365 nm UV light....
a, Transcription factors search for targets in a local interaction hub by a bound-state-dominant mode. Local exploration is proposed to be guided by transient interactions with other co-regulators (proteins or non-coding RNAs) in the hub; TF, transcription factor.b, The diagram illustrates the ...
a, Schematic of the MY-LC study. Numbers indicate the number of participants after exclusion (Methods). The diagram was created using BioRender.b, Select demographic information for the LC (top row, purple) and CC (bottom row, yellow) groups. The centre values in the ‘age’ column represe...
Schematic diagram illustrating the preparation of Ni-N/OMC (color online). View Download Figure 2 Morphology of 3D ordered micro-macroporous single atom nickel electrocatalyst Ni-N/OMC-1 anchored to carbon. (a–c) SEM images; (d, e) bright-field TEM images at different magnifications; (f...
A density-functional study of the phase diagram of cementite-type (Fe,Mn)3C at absolute zero temperature properties with changes in the electronic and magnetic structures by means of bonding analyses using the Crystal Orbital Hamilton Population (COHP) technique... JV Appen,B Eck,R Dronskowski...
nism, CO oxidation on PN2C1-G is more favorable Scientific Reports | Vol:.(1234567890) (2022) 12:10439 | https://doi.org/10.1038/s41598-022-14286-8 6 www.nature.com/scientificreports/ Figure 5. The potential energy surface diagram of CO oxidation via the first step in an ER...
The detailed schematic diagram of ESTEM can be found in Supplementary Fig. 20. It is generally known that Ni nanoparticles could be oxidized to form superficial NiO layers upon exposure to air at ambient conditions, which inevitably ruined original surface configurations of the reduced catalyst. In...
FIG. 1 is a schematic circuit diagram of an organic light emitting display device of the present disclosure. FIG. 2 is a schematic cross-sectional view of an organic light emitting display device according to a first embodiment of the present disclosure. FIG. 3 is a schematic cross-sectional...