Comparison with Cl-transfer data of other chloromethanes and chloroethanes shows that an increase in the C Cl bond dissociation energy is the main cause of the reduced reactivity of CFCl 3 . Based on a previously developed correlation, D (CFCl 2 Cl) is estimated to be equal to 74.4 ...
Energy flow and C–H and C–Cl bond dissociations in o-chlorotoluene (OCT) in collisions with H2, Cl2, and HCl are studied using classical trajectory methods. The energy loss by the excited OCT is small, but it increases with increasing total vibrational energy content ET of OCT between 50...
Argon chloride (Ar2Cl2 and Ar3Cl2): structure, bond energy, and dissociation dynamics 来自 Semantic Scholar 喜欢 0 阅读量: 45 作者:Bieler, Craig R,Evard, Dwight D,Janda, Kenneth C 摘要: Publication » Argon chloride (Ar2Cl2 and Ar3Cl2): structure, bond energy, and dissociation ...
Through the introduction of the dissociation energy and equilibrium bond length as explicit parameters for a diatomic molecule, the improved versions have been achieved for the well-known Manning-Rosen, Rosen-Morse, Frost-Musulin, Tietz, and Pöschl-Teller oscillators [16], [17], [18]. Recent...
We have summarized the thermochemistry of chlorine adsorption on Au(111) and estimate that the dissociation energy of the Cl-Au bond, D (Au-Cl) is about 54 kcal/mol. This is at least 20 kcal/mol smaller than on Ag.doi:10.1016/0169-4332(93)90030-FGeorge N. Kastanas...
energy efficiency of the system. Li et al.26examine the efficiency of Kr/Cl2excilamp for the disinfection of waterborne pathogens. Kr/Cl2excilamp developed by them provides an intensity of 0.03–0.3 mW/cm2by utilizing the power from 15 to 60 W. Xu et al.8reported the degradation of 46...
We have summarized the thermochemistry of chlorine adsorption on Au(111) and estimate that the dissociation energy of the Cl-Au bond, D (Au-Cl) is about 54 kcal/mol. This is at least 20 kcal/mol smaller than on Ag. 展开 关键词: Experimental/ adsorption Auger effect chlorine desorption ...
摘要: Geometrical parameters and vibrational frequency data for the dimer of monochlorogallane obtained by ab initio calculations show excellent agreement with experimental values; the dissociation energy of Ga2Cl2H4 to the GaClH2 monomers and GaCl + H2 has been calculated. 关键词: RAMAN SPECTROSCOPY...
ChemInform Abstract: Ar2Cl2 and Ar3Cl2: Structure, Bond Energy, and Dissociation Dynamicstheory, structureargon, Arvisible and UV spectra (atoms and moleculesExcitation spectra and fragment Cl 2 distributions are measured for Ar 2 Cl 2 and Ar 3 Cl 2 .doi:10.1002/chin.199051002...
The calculated bond dissociation energy of Cl 2 (PH 3 ) 3 ReN–AlCl 3 is D e =43.7kcal/mol, which is nearly as high as the bond energy of Me 3 N–AlCl 3 . The donor-acceptor bonds of the other Cl 2 (PH 3 ) 3 ReN–AY 3 complexes are also very strong. Even stronger N–X...