A major role in the increase in the activation energies is played by the formation of the intermediate electrostatic Van der Waals' complexes. For the complex cis -[Pd(NH 3 ) 2 Cl 2 ], the activation barriers in the nucleophilic substitution reaction are considerably lower than those for ...
G. Hill, R. W. Gora, S. Roszak, and J. Leszczyński∗, "The Structures and Properties of Cis- and Trans-MeCl2(NH3)2, Me=Pd and Pt Complexes, in Ground and Excited States", Int. J. Quantum Chem. 2001, 83, 213-219 (IF: 1.249, CI: 5). doi: 10.1002/qua.1212....
8.钌多吡啶配合物[Ru(phen)2CPIP](PF6)2 9.钌配合物[Ru(NH3)4LDLA]n+ 10.手性钌配合物Δ-[Ru(bpy)2(o-tFPIP)](PF6)2 11.Δ-[Ru(bpy)2(p-tFPIP)](PF6)2 12.Δ-[Ru(bpy)2(m-tFPIP)](PF6)2 13.钌(Ⅱ)多吡啶配合物[Ru(dip)2(DBHIP)](ClO4)2 ...
The reactions of Pt(II) complexes, cis-[Pt(NH3)2Cl2], [Pt(terpy)Cl]+, [Pt(terpy)(S-cys)]2+, and [Pt(terpy)(N7-guo)]2+, where terpy = 2,2′:6′,2... Dejan,Petrović,and,... - 《Bioorganic & Medicinal Chemistry》 被引量: 9发表: 2007年 加载更多来源...
trans-[Pt(NH 3) 2Cl 2]The K absorption-edge spectra of the ligand chlorine ion in square-planar complex compounds cis- and trans-[Pt(NH 3) 2Cl 2], trans-[Pd(NH 3) 2Cl 2], and (NH 4) 2PdCl 4 are reported and discussed in connection with the chlorine K absorption spectra of...
Spin–lattice relaxation 'null times' have been obtained for cis- and trans-Pd(NH3)2Cl2. The presence of a low temperature minimum for the trans complex has been interpreted in terms of inequivalent ammine groups. The second moment values are consistent with both ammine groups in both ...
An assessment of the cytotoxicity of these new complexes indicated that both metal complexes demonstrate a moderate activity at 6–10% of that of anticancer drug [Pt(NH3)2Cl2] (cisplatin) which was used as a positive control. The Pd(PiCO)2 complex has shown has shown similar – and rather...
Fisher, "Studies on the synthesis, characterization, binding with DNA and activities of two cis-planaramineplatinum(II) complexes of the formml: cis-PtL(NH3)Cl2 where L = 3- hydroxypyridine and 2,3-diaminopyridine," BMC Chemical Biology, vol. 6, article 3, pp. ...