CIS-(1S,2R)-3-METHYL-3,5-CYCLOHEXADIENE-1,2- DIOL 英文别名: CIS-1,2-DIHYDRO-3-METHYLCATECHOL;cis-3-methyl-3,5-cyclohexadiene-1,2-diol;20w/v%solutioninethylacetate,stab.with0.2%ea;CIS-1,2-DIHYDROXY-3-METHYLCYCLOHEXA-3,5-DIENE;CIS-(1S,2R)-3-METHYL-3,5-CYCLOHEXADIENE-1,2- DIOL...
The cis-dihydrodiol metabolites, formed by TDO-catalyzed dihydroxylation, exclusively at the 2,3-bond of monosubstituted benzene substrates except for fluorobenzene, were enantiopure (>98% ee) [4,5,6,7,8,9]. Conversely, the isolated thiophene dihydrodiol metabolites were found to be mixtures of...