Charge-transfer interaction of picryl chloride with acenaphthene, biphenyl, m-terphenyl, o-xylene, and m-xylene is studied in CHCl 3 . Charge-transfer spectra of these complexes are examined spectrophotometrically. The formation of 1:1 molecular complexes is observed in each case. The association...
Charge Transfer ComplexPinacyanol ChlorideSpectroscopyOptoelectronic DevicesDiodesLEDsSolar CellsOrganic photoconductor, pinacyanol chloride, has been studied with infrared spectroscopy because of its thermal activation energy () and band gap (= 2) lying in the infrared range. Particularly, pinacyanol ...
Charge-transfer complexPolymerization of non-conjugated divinyl monomer N,N'-methylenebisacrylamide was studied using a novel charge-transfer complex of N,N-dimethylaniline-benzenesulphonyl chloride in a homogeneous gel-free state, under varying conditions of concentration and temperature. The reactions ...
For the polymer complex solution and 1,3-diphenyl-propane solution, strong charge-transfer bands have been observed in the wavelength region at about 380 to 500 nm, where no band is observed in benzene derivatives. This strong charge-transfer band is considered to be due to the strong ...
It was also shown that, upon reaction with HCl, 3 equilibrates with the [Ir(1)HCl2] complex 7. 展开 关键词: photochemistry charge transfer iron complexes DOI: 10.1021/ic980353n 被引量: 19 年份: 1998 收藏 引用 批量引用 报错 分享 ...
charge-transfer complexgreen luminescenceUV irradiationA wide emission band located at 530 nm was observed upon UV irradiation of the dimethylformamide solution of EuCl 3 with excess of the chloride anions in the solution. Intensity of the emission band was found to be several times higher as ...
The resulting hydrate, like many other neodymium salts, has the interesting property that it instantly and reversibly turns light yellow under fluorescent light (see picture).The color change is likely due to the charge transfer converting the Nd3+ ions into the Nd2+ state; the orange absorption...
charge-transfer complexescrystal structurelignocainemanganese chlorideThe crystal and molecular structure of lignocaine hydrochloride-manganese chloride complex, MnCl4C28H44O2N4, is reported. The sample crystallizes in the space group P 2(1)/c with a = 9.210(2) Angstrom, b = 19.489(4) Angstrom,...
correlations between photocurrent decay traces and CV studies were also observed.Keywords: dye-sensitized photoelectrochemical cell; charge transfer; chloride anions; titaniumdioxide; ruthenium catalyst; electron transfer; hole-hopping1. IntroductionIn nature, solar energy is stored in the form of chemical...
Free radical and charge-transfer complex intermediates. Benzidine and related compounds are well known substrates for horseradish peroxidase/H2O2 oxidation. Typically, two different colored products are formed. In this paper, we study the oxidation of 3,5,3',5'-tetramethylbenzidine. The first... ...