The theoretical and experimental studies on the chiral self-sorting reveal that the exclusive self-recognition on cage formation is an enthalpy-driven process while the chiral narcissistic and self-sorting on supramolecular assembly of racemic cages can be precisely regulated by π–π and C–H…π...
Chiral self-sorting is a phenomenon wherein racemic components are spontaneously sorted into homo- or heterochiral molecular assemblies through chiral discrimination between the components. Chiral self-sorting may be related to biological molecular systems where chiral biomolecules are concerned, but the det...
Chiral self-sorting and guest recognition of porous aromatic cages Article Open access 11 July 2022 Preferential molecular recognition of heterochiral guests within a cyclophane receptor Article Open access 16 January 2023 Engineered non-covalent π interactions as key elements for chiral recognition...
Chem. Int. Ed.在线发表我院有机功能材料团队宋金同博士关于高性能金属配位诱导面手性光学材料的最新研究成果“Metal-Induced Planar Chirality of Soft-Bridged Binuclear Platinum(II) Complexes: 100% Phosphorescence Quantum Yields, Chiral Self-Sorting, and Circularly Polarized Luminescence”(Angew. Chem. Int....
Constitutional self-sorting of homochiral supramolecular helical single crystals from achiral components 来自 国家科技图书文献中心 喜欢 0 阅读量: 36 作者:Fiorina Dumitru,YM Legrand,AVD Lee,M Barboiu 摘要: Double-helical architectures obtained from achiral ligands and metal ions present supramolecular homo...
Singlecrystal X-ray diffraction of these smaller Fe_2~(II)L_3 cages revealed several non-covalent interactions as a driving force for narcissistic chiral self-sorting. This expected behavior was confirmed utilizing the shorter ligands in racemic form, yielding discrete, homochiral Fe_2~(II)L_3 ...
Barboiu.Constitutional self-sorting of homochiral supramolecularhelical single crystals from achiral components. Chemical Communications . 2009Dumitru F,Legrand Y.M,Lee A.V.D. et al.Constitutional self-sorting of homochiral supramolecular helical single crystals from achiral components.Chemical Communications...
Interestingly, a self-sorting behavior between the open form and closed form in the self-assembly was observed (Figures S17 and S18). This finding indicated that the ring-open form and ring-closed form could not be assembled into one single metallacycle in this case because of their ...
Activity induced synchronization: from mutual flocking to chiral self-sorting. Phys. Rev. Res. 1, 023026 (2019). Article CAS Google Scholar Levis, D. & Liebchen, B. Simultaneous phase separation and pattern formation in chiral active mixtures. Phys. Rev. E 100, 1–8 (2019). Article ...
NG108 cells differentiated into completely dissimilar neuron-like morphologies on thel- andd-Pen-NP films. These insights could open up an avenue to reveal the chiral self-sorting between the chiral molecules modified film surface and cytomembrane proteins. Noninvasive cell retrieval was achieved with...