Brønsted basicity is a fundamental chemical property featured by several kinds of inorganic and organic compounds. In this Review, we treat a particularly high basicity resulting from the mechanical entanglement involving two or more molecular subunit
In this review, we briefly introduce the formation and constraints of the three-phase interface and propose three criteria to judge its merit, namely, the active site, mass diffusion and electron mass transfer. Subsequently, a series of modulation methods and relevant works are discussed in detail...
and semiconducting characteristics. The fused donor-acceptor-donor (DAD) molecule showed typical p-type characteristics with a hole mobility of 1.1 × 10−3cm2V−1s−1. We also achieved the synthesis of a D-A type copolymer containing the fused DAD structure as an electron donor unit. ...
The solid-phase chemistry literature from the 1960s to 1997 has been reviewed with an emphasis on organic chemistry. Reactions have been classified according to the products formed on the solid phase, the types of chemistry performed, names of chemical reactions, asymmetric reactions and transition ...
Herein, we report a facile and effi-cient strategy to modulate the molecular orbital energies, charge transport capacities, and spin electron densities of the active units in covalent organic frameworks (COFs) via regulating the conjugated unit size to optimize the redox activity and stability of ...
The simple class of dinuclear Mn(I)carbonyl compounds with phosphido (PR2−) and hydrido (H−) bridges has been known since the 1960’s. Only recently were they discovered to have potential catalytic applications. This Review is a fresh look the synthesis, reactivity, and catalysis of this...
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Along with offering a detailed understanding of the nutritional attributes of guava seeds, the present review comprehensively elaborates on the therapeutic activities of their bioactive compounds, their techno-functional properties, and their other edible and nonedible applications. The limited molecular ...
Synthesis ofL-Hexopyranosyl Fluorides Enabled by Radical Decarboxylative Fluorination: Assembly of a Pentasaccharide Repeating Unit Corresponding to Extracellular Polysaccharide S-88 Zhi Qiao, Dongwei Li, Jingru Gao, Zijiao Hou, Ningjie Yan, Ni Song, Peng Wang,* and Ming Li* ...
Blaise C, Gagné F, Eullafrroy P, Férard JF: Ecotoxicity of selected pharmaceuticals of urban origin discharged to the Saint-Lawrence River (Quebec, Canada): A review. Braz J Aquat Sci Technol. 2006, 10: 29-51. Article Google Scholar EUCAST (European Committee for Antimicrobial Susceptibili...