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Divalent lanthanoid pseudo-Grignard reagents PhLnBr (Ln=Sm, Eu and Yb) can be easily prepared by the oxidative addition of bromobenzene (PhBr) to lanthanoid metals in tetrahydrofuran. PhLnBr reacts with bulkyN,N′-bis(2,6-di-isopropylphenyl)formamidine (DippFormH) to generate LnIIcomplexes...
It has been observed that when plants are supplied As(V), typically more than 90% of the As in the roots and the shoots was found to be in the form of As(III) [29,30,32]. Thus, As(V) is readily reduced to As(III) by plants. This reduction is accepted as the first step i...
Zoubi, A. W.; A-Hamdani, S. A. A.; Ahmed, D. S.; Ko, G. Y. A new azo-Schiff base: synthesis, characterization, biological activity and theoretical studies of its complexes.Appl. Organomet. Chem.2017,32, e3895;https://doi.org/10.1002/aoc.3895.Search in Google Scholar ...
In the case of Re(CO) 3(PPh 3)(RL ) seven nearly equispaced lines are observed due to virtually equal coupling with metal and 31P ( I=1/2) nuclei. The g values of the radical species span the range 2.0033–2.0066.doi:10.1016/j.jorganchem.2004.02.034Bikash Kumar Panda...
Nanoparticles can form particle clusters with larger particle sizes through in-situ aggregation in the pore throats to block water channels. This study provides a new method for the equilibrium between nanoparticle injectivity and in-depth profile control in low permeability reservoirs. Abstract Full ...
form membraneless organelles inEscherichia coli. To do this, we combine de novo α-helical sequences, intrinsically disordered linkers and client proteins in single-polypeptide constructs. We tailor the properties of the helical regions to shift protein assembly from arrested assemblies to dynamic ...
Wu, G. & Kwan, I. C. Helical structure of disodium 5′-guanosine monophosphate self-assembly in neutral solution. J. Am. Chem. Soc. 131, 3180–3182 (2009). CAS PubMed Google Scholar Nakayama, S., Kelsey, I., Wang, J. & Sintim, H. O. c-di-GMP can form remarkably stable G...
Phytic acid, the main storage form of phosphate in maize (Zea mays L.) grains, is known as antinutrient due to its chelating properties but may also prevent oxidation. Thus, the impact of phytic acid on the degradation of tocochromanols, carotenoids, fatty acids, and oxidation products in ...
Jasmine Panda: Writing – review & editing, Software. Chita Declaration of competing interest We declare that we have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. Acknowledgements Author SN expresses gratitude to...