Precursors for the release of phosphorus mononitride in solution under mild conditions have remained elusive. Now, an explosive anthracene-stabilized azidophosphine has shown PN transfer reactivity in the synthesis of an Fe–NP complex. The PN ligand is N-bonded, as the Fe–N interaction shows si...
Single-atom catalysts are a promising class of catalytic materials, but general synthetic methods are limited. Here, the authors develop a ligand-mediated strategy that allows the large-scale synthesis of diverse transition metal single atom catalysts supported on carbon. Hongzhou Yang Lu Shang Tierui...
-Perovskite Solar Cells.While solution processing significantly reduces the threshold and cost of perovskite solar cells, the intricate composition and nonequilibrium nucleation of the perovskite precursor can result in leaky films. Yanlin Song (宋延林), Na Wang...
15N Schiff bases (see scheme) have been demonstrated to be a new class of substrates effectively hyperpolarized by Signal Amplification by Reversible Exchange (SABRE). Abstract Full text PDF References Request permissions Protein Crystal Structures Structural Basis for Bulky-Adduct DNA-Lesion ...
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Dicopper(II) Mozobil™: a dinuclear receptor for the pyrophosphate anion in aqueous solution Supramol. Chem., 29 (2017), pp. 834-845 CrossrefView in ScopusGoogle Scholar 25 K. Gratzer, V. Diemer, J. Clayden Signal transduction in oligoamide foldamers by selective non-covalent binding of...
Maillard reaction is pH-responsive, the influence of solution pH on the formation kinetic and antioxidant activity of MRPs was therefore evaluated in this work. FT-IR and zeta-potential results confirmed the formation of MRPs between chitosan and corn syrup solids. Possible Amadori compounds ...
Lindquist N, Fenical W, Van Duyne GD, Clardy J (1988) New alkaloids of the Lamellarin class from the marine ascidianDidemnum chartaceum. J Org Chem 53:4570–4574 CASGoogle Scholar Carroll AR, Bowden BF, Coll JC (1993) Studies of Australian ascidians. I. Six new lamellarin-class alkaloid...
Due to the huge number and variety of catenane and rotaxane structures, it is not surprising that most of the time enhancements of basicity due to molecular entanglement were serendipitously found in this class of molecules. Entanglement-driven enhancement of basicity in catenanes Catenanes are constit...
This knowledge is directly relevant for developing advanced decision-making frameworks that can automatically decide on the most optimum combination of computational methods for a target class of chemical compounds. Methods Thermodynamic principle The reaction energy difference between the reactant and ...