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They have successfully demonstrated the co-doping of S and N atoms into the lattice of GQDs. Kim's group [154] fabricated various doped GQDs by dissolving organic materials in different solvents. As shown in Fig. 16d, catecholamine was first dissolved in water and N, N-dimethyl sulfoxide (...
5e–g, where for each pair of ions, there is remarkably good correlation between the residue-specific sum of the mL for the two ions separately and the mL for the mixture of both ions together. Fig. 5: mL for amide protons on titration with pairs of Hofmeister ions. a–c Values for ...
Crystal structures of both the folded and twisted conformers were obtained for 5a and 5e. Surprisingly, both the folded and twisted conformers were present in one unit cell, in ratio 1:1. This is the first examples of BAEs containing both conformers in one crystal. The structure of ...
(III)derivativesofaetio-porphyrin-Iwerealsopre-paredbyasimilarmethod.Thefirst-rowtransitionmetalderivativesoforganometallo-porphyrinswerethussynthesizedforthefirsttime.Inanalternativesynthesis,Johnsonandhisco-workerswerealsoabletopreparetheidenticalalkylcobalt(III)aetioporphyrin-Icomplexesasthatmentionedabove,by...
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The ΔG′/Δt values, which serve as an index for the photoreactivity of the resins, were extracted from the first three minutes of the photorheology curves (Fig. 5E) and are presented in Fig. 5F. Significant differences were observed between dECM-MA and dECM-GMA resins with similar dE...
Josiah Parsons Cooke, the Natural Philosophy of Sir John F. W. Herschel and the Rational Chemistry of the Elements The natural philosophy of chemistry grew slowly until the articulation of the axiom of chemical atoms by John Dalton in the early nineteenth century. Sir John F. W. Herschel was...
CLs are regarded as highly oxygenated triterprenoids as they contain relatively high numbers of oxygen atoms (7–11) in their structures. CLs are found as both free aglycones and corresponding β-D-glucosides, the former mostly occurring in seeds while the latter are formed during fr...
5e (refer to the “Methods” section for the calculation of free energy). It has been shown that for three-body interaction the optimally packed cluster can only form when the third methane is placed symmetry relative to the methane dimer37. As a result, we select the distance between the...