Moreover, the aqueous Zn/MnO2 battery with BIS-TRIS as electrolyte additive delivers an 86% capacity retention after 600 cycles at 500 mA g-1. This zinc-chelating coordination based facile strategy opens a new window for the future development in dendrite-free Zn anode....
A combination of chelating agents (sodium diethylenetriamine-pentaacetate (DTPA) and salicylate) were introduced to the treatment solution. The role of each additive and the influence of treatment bath composition on the LDH formation processes are discussed. A synergistic effect of DTPA and salicylate...
In this work, calcium gluconate (CG), a chelating agent, as a novel electrolyte additive was introduced to tackle the thorny issue of zinc anodes in a 2 M ZnSO4 electrolyte by the synergistic effects of gluconate (GA) anions and Ca2+ cations. Experimental characterization and computational ...
Specifically, through the derivation of Bb, it was possible to adjust the Zn2+ solvation structure, decreasing the coordinated active SO42/H2O and promoting the anchoring of these species on the surface of the zinc anode. This process provided electrostatic shielding and isolates the SO42/H2O, ...
As verified by theoretical modeling and experimental investigations, the benzenesulfonic acid groups on the additive molecular not only facilitates its water solubility and selective adsorption on the Zn anode, but also effectively accelerates the de‐solvation kinetics of Zn2+. Meanwhile,...
A combination of chelating agents (sodium diethylenetriamine-pentaacetate (DTPA) and salicylate) were introduced to the treatment solution. The role of each additive and the influence of treatment bath composition on the LDH formation processes are discussed. A synergistic effect of DTPA and salicylate...