β-Elimination-immune PCcarbeneP iridium complexes via double C–H activation: ligand–metal cooperation in hydrogen activation. Organometallics 31, 2949–2952 (2012). Article CAS Google Scholar Gessner, V. H., Becker, J. & Feichtner, K.-S. Carbene complexes based on dilithium methandiides....
Some protein corona may increase the targeting capability, while some leads to a decrease in the targeting efficiency since targeting ligand to the receptor of the cell membrane is shield. Protein corona also changes the drug release profile of nanocarriers. Therefore, more research work is needed ...
This different values of total charge of the ligands can have effects on the docking results? For example for ZINC000001644610.mol2 openbabel evaluate a total charge equal -2 whereas mk_prepare_ligand.py returns the following output when the previous molecule is processed: Processing ./ZINC0000016...
Optical excitation of the complex leads to population of metal-to-ligand charge transfer excited states and at least two distinct intraligand charge transfer excited states. Several experimental observations are consistent with charge injection by excited Re*. These include similarity between TRIR spectra...
the electronic properties is investigated through a comprehensive photophysical and theoretical study on the two complexes in comparison to reference complexes without substituents on the ancillary ligand ([l][PF6] and [2][PF6]) and by making absorption and luminescence titrations of ligand pyr2bpy....
The influence of the magnetic interaction between a paramagnetic metal ion and a radical ligand upon the spectroscopic (UV-vis and/or NMR) properties will be described and discussed mainly for the mixed ligand complexes, M(L)(X) (M = Ni(... Kaizaki,Sumio - 《Bulletin of the Chemical Soc...
Kober, EM, Sullivan, BP, Meyer, TJ (1984) Solvent dependence of metal-to-ligand charge-transfer transitions. Evidence for initial electron localization in MLCT excited states of 2,2′-bipyridine complexes of ruthenium(II) and osmium(II). Inorg Chem 23: pp. 2098-2104...
The data were found to be consistent with a mechanism involving a Ru(IV) species hi which the ampy ligand is deprotonated, and this intermediate subsequently undergoes a two-electron transfer (accompanied by deprotonation) to give the imine product. The various rate constants for the individual ...
Semiconductors based on heavy pnictogens (namely Sb3+and Bi3+) have gained a surge of interest over the past few years because of their potential to replicate the defect tolerance of lead-halide perovskites (LHPs), whilst overcoming their toxicity and stability limitations1,2,3,4,5,6. Defect...
39 As a matter of fact, the outcome generated by such a state will depend on its energy with respect to both ligand and metal-ion levels and on the importance of the crossing over between this state and, in the case of EuIII, the 5D and/or 7F terms. A theoretical approach has been...