Application of time-resolved infrared spectroscopy to electronic structure in metal-to-ligand charge-transfer excited states. Infrared data in the nu(CO) region (1800-2150 cm(-1), in acetonitrile at 298 K) are reported for the ground (nu(gs)) and polypyridyl-based, metal-to-ligand... DM...
Univ. Leuven, B‐3001 Leuven, Belg.John Wiley & Sons, LtdChemInformHendrickx M F A,Mironov V S,Chibotaru L F,Ceulemans A.An ab initio study of the ligand field and charge-transfer transitions of Cr(CN)63- and Mo(CN)63-. Journal of the American Chemical Society . 2003...
The strength of the interaction is then the product of the value of the quadrupole moment (a constant for each nuclei) and the field gradient, which depends on the crystal structure, ligand type, and orientation around the resonant nuclei. The strength of this interaction for an axially ...
An influential review of metal–ligand cooperativity. Article CAS Google Scholar Chatterjee, B., Chang, W.-C., Jena, S. & Werlé, C. Implementation of cooperative designs in polarized transition metal systems — significance for bond activation and catalysis. ACS Catal. 10, 14024–14055 (...
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Electrostatic interactions between charged groups are likely to play essential roles in molecular processes involving proteins, including ligand-binding, protein-protein interactions, and protein folding-unfolding. In fact, recent work supports that charge-charge interactions are the main determinants of the...
the Ce3+which substitutes for Y3+in the site of D2symmetry has 8 nearest neighbour oxygen atoms. The eightfold coordination of Ce3+in the dodecahedral site can be described as a cubic coordination with an additional tetragonal distortion. According to the ligand field theory, the 5d state will...
Application of time-resolved infrared spectroscopy to electronic structure in metal-to-ligand charge-transfer excited states. Infrared data in the nu(CO) region (1800-2150 cm(-1), in acetonitrile at 298 K) are reported for the ground (nu(gs)) and polypyridyl-based, metal-to-ligand... DM...
The reaction mechanism of Co2+ metal ion and bidentate ligand 1, 2 benzene dicarboxylic acid (BDC) is given below11: $${{{\rm{Co}}}^{2+}+{2{{{\rm{e}}}^{-}\,\leftrightarrow {{{\rm{Co}}}^{0}$$ (3) $${{{\rm{NO}}}_{3}}^{2+}+{4{{{\rm{H}}}^{-}+{4{{...
Correlation Between the Lever Parameter and Electronic Properties of Nitrosyl Ruthenium(II) Complexes The Lever parameter (EL), for a series of ruthenium nitrosyl complexes of the type [Ru(NH3)4NOL] n+, where ligand L = nicotinamide (nic), isonicotinamide (isn), pyrazine (pz), pyridine (py...