a renewable C1 feedstock, and then stored as chemical bonds; however, the development of effective catalysts for generating CO2•‒radicals and converting them into CH3OH as much as possible is crucial to the success of this strategy. In irradiated...
The reaction proceeds via the formation of a pre-reactive complex (RC1) with C1point group of symmetry in which the H of OH group is directed towards O of CH3OH. The energy of RC1is 4.97 kcal mol−1lower than the reactants and is in good agreement with the previous theoretical values...
L (L=HCl, MeOH) acid–base complexes. Our calculations reveal that 1-G , 3-MG , and 5-MG interact more strongly with MeOH than HCl due to the positive hydrogen bond cooperativity. Furthermore, the carbonyl site on G is found to be the most reactive site, while methyl substitution ...
Chemical and electrochemical synthesis of a series of cobalt(II), nickel(II), copper(II), and zinc(II) complexes of tridentate Schiff base (H 2 L), a product of condensation of N-(2-aminophenyl)-4-methylbenzenesulfonamide (2-tosylaminoaniline) with 1-phenyl-3-methyl-4-formylpyrazol-5-...