Organofunctionalized alkyltin bromides have been synthesized from solvochemically activated tin metal and the corresponding alkyl bromide under mild conditions (95°C) and without the use of a catalyst. This synthetic method tolerates a variety of functional groups such as chloride, cya...
We analyze its crystal structure by X-ray Diffraction (XRD), chemical composition by infrared spectroscopy(IR).The results show that DMMnF belong to trigonal system, space group is R3-CH, the lattice constant is a=8.3330 (17) Å, c= 22.947 (11) Å, γ=120°,V=1379.09 (10) Å3...
This synthetic method tolerates a variety of functional groups such as chloride, cyanide, or a carboxylic ester and can be applied to different chain lengths. Crystal structure analysis of as-prepared [(H3COOCC2H4)2SnBr2] shows a close-to-octahedral environment for the tin atom, created by...
The calculated charge distributions by Natural Population Analysis show that the charge transfers exist between the functionalized group and parent C 60. Then, the excited state properties of title species are calculated by the time-dependent density functional theory. It is shown that the fullerene ...