Thermal transformations of the well-known high spin manganese carboxylate cluster [Mn12O12(CH3COO)(16)(H2O)(4)].4H(2)O.2CH(3)COOH have been studied in detail. Three steps in its thermal transformation have been observed with the successive formation of ...
The crystal structure consists of Cu-2(CH3COO)(2)(CH3COO)(1/2)(OH)(4/3)H2O1/6+ dimers that are interconnected by Cu(CH3COO)(CH3COO)(1/2)(OH)(2/3)(1/6-) squares forming chains running in the c-direction. Non-coordinating hydrate water molecules are intercalated inbetween the...
E. B. Coropceanu, L. Croitor, A. V. Siminel, M. S. Fonari, Unique tetranuclear heterometallic compound [Na2Zn2{(4-py)C(H) (NOH)}2(CH3COO)6(H2O)4]*2H2O with luminescent properties. Inorg. Chem. Commun. 2011, 14, 1528....