Molecular complexesLigandsPhenyl radicalsη 6,η 6-Dimethyldiphenylstannane-bis-tricarbonylchromium, (CH 3) 2Sn[C 6H 5Cr(CO) 3] 2 crystallizes in the orthorhombic space group Pna2 1 with Z 4, a 2663(2), b 1032.0(8), c 762.7(3) pm, V 2096 x 10 6 pm 3. The crystal structure ...
The valid strong THz absorption at 1.58 THz was probed in the organic-inorganic hybrid perovskite thin film, CH3NH3PbI3, fabricated by sequential vacuum evaporation method. In usual solution-based methods such as 2-step solution and antisolvent, we ob
ChemInform Abstract: CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF (OC)4WPPH2CH(CH2CH2PPH2)CH2PPH2.CH3CO2C2H5. FREE RADICAL ADDITION OF DIPHENYLPHOSPHINE TO A COORDINATED PHOSPHINOALKENEChemInform Abstract: CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF (OC)4WPPH2CH(CH2CH2PPH2)CH2PPH2.CH3CO2C2H5. FRE...
As already noted for ACPLs in general [15,16,17] and recalled in the previous section, inputs in which an sp2 O not engaged in an IHB is co-planar to the benzene ring do not change significantly when R = H, whereas they optimise to a geometry in which the acyl group rotates so ...
CO2•‒anion radicals, once formed in solutions, are likely to undergo disproportionation to formate and CO or recombine to oxalate9,10, so another major challenge is to direct them toward CH3OH, which can suppress the yield of undesired by-products. Copper (Cu) is the best-known metal ...
Molecular structure of Fe... trans-Fe(Ph2PPY)2(CO)3 reacts as a neutral tridentate ligand with Mo(CO)6, Ni(NCS)2, [Rh(CO)2Cl]2, CuX (Cl, Br, I) and Hg(SCN)2 to form binuclear complexes including an Fe-M bond. Crystal and molecular structures of the Fe-Hg complex has......
小分子和自由基 在过渡金属团簇上的吸附行为也逐渐受到了研究者 的关注. CHn (n=1,2,3,4)小基团, CO 分子, NO 分子, O2 分子及某些大的有机分子在金属上吸附的研究也有 报道[3–5]. Poveda 等人[6]利用 MINDO/SR 方法研究了 CHn(n=1,2,3)在 Ni14 团簇上的吸附能, 吸附能的大小顺 序为 CH3...
Cryst.Res.Technol.3419997925–928Thetitlecompound[La(NO3)6{Cu(2,2’-bipy)2}2][La(NO3)6Cu(2,2’-bipy)2]•CH3CNwassynthesized,thecrystalandmolecularstructuresweredeterminedatroomtemperature.Thecomplexformedmonocliniccrystals,spacegroupP21/n(No.14),,a=10.354(3)Å,b=23.440(9)Å,c=32.817(...
Molecular structureA new carborane, 5-(CH3)3N(+)- 2,4-C2B4H6(-), has been prepared from the reaction of closo-1,6-C2B4H6 and trimethylamine. ... Lockman, B,Onak, T 被引量: 5发表: 1972年 Synthesis, structure and reactivity of highly constrained-geometry yttracarborane alkyl [σ:η...
2,3. CH3OH abundances are also dominated by direct emissions, but some sources also include the oxidation pathways of methane and from other volatile organic species. The oxidation of methanol forms species that includes carbon monoxide (CO), formaldehyde (HCHO), and tropospheric ozone (O3). ...