Crystal Field Theory simply: a ligand lone pair(孤对电子) is modelled as a point charge that repels electrons in the d orbitals of the central metal ion.下图显示的是金属d轨道的空间构型:2. 正八面体配位体Octahedral complexes本章节基础知识详参数学几何中的群论。在此我不多做解释。我很喜欢几何...
Figure 02: Splitting Pattern in Octahedral Complexes Splitting Pattern Since there are five d orbitals, the splitting occurs in a ratio of 2:3. In octahedral complexes, two orbitals are in the high energy level (collectively known as eg) and three orbitals are in the lower energy level (coll...