To better understand the charge/spin dynamics of active-site nonheme FeIII/FeIIduring the reaction, we drew on the natural bond orbital (NBO) analysis. FeIIIin both intermediate-spin (IS) and high-spin (HS) states has the same natural electron configuration (NEC) as [core] 4 s0.203d6....
had tested fivedifferent Lewis acids, but only AlCl3could catalyse the reaction effectively.[11]Except that, no further attempt for 2searching other catalyst was carried on. The defects of AlCl3as catalyst are mainly: (1) the sensitivity tohumidity and (2) the degradation side reaction on ...
It is first initiated by the reaction of e− with O2 to create O2•−, and then the O2•− combines with H+ to produce HO2•−. Hence, H2O2 is produced as the intermediate. Finally, OH• radicals can be advanced through the separation of H2O2. Thus, the O2•− and...
(a) Change between pH value and reaction time; (b) Change between conductivity and FigurrerFeeai4agc.cuttiroi(oeann)4tti.Cmim(hae)ea..nCgheanbgeetwbeetewneepnHpHvavlualeueanadndreraeacctitoionn ttiimmee;; ((bb))CChhaanngegebebtewteweneecnoncdouncdtiuvcittyivaitnyd and r3e.a2c. tDio...