Ketones and aldehydes are hydrogenated to the corresponding alcohol or alkyl group, using H2 gas as the stoichiometric reductant, and organometallic ruthenium complexes as the catalysts.バロツクアールモリスフアガンポールジヨセフハウプトマンエリザベスエムシユラフマルセル...
Catalytic Synthesis of Aldehydes and Ketones Under Mild Conditions Using TEMPO/ Oxone. Org. Lett. 2000, 2(8), 1173-1175.Bolm, C.; Magnus, A.S.; Hildebrand, J.P. Catalytic synthesis of aldehydes and ke- tones under mild conditions using TEMPO/oxone. Chem. Lett. 2000, 2 (8), 1173-...
aldehydesketonesMeerwein-Ponndorf-Verley reductionCatalytic Meerwein-Ponndorf-Verley (MPV) reduction of various aliphatic, aromatic, and unsaturated aldehydes and ketones to corresponding alcohols (analyzed by GC-MS) in the presence of boron triethoxide (B(OEt)3) were studied. Kinetics of this ...
The reductive amination of aldehydes or ketones using Ph(2)SiH(2) or PhSiH(3) has been effectively promoted by the direct use of Bu(2)SnClH-pyridine N-oxide as a catalyst; this method has advantages in terms of its mild conditions and wide application to various carbonyls and amines, in...
The reductive amination of aldehydes and ketones is one of the most useful routes to secondary amines, in which the three components of carbonyl, amine and reductant are easily combined in one pot.1The advantage of this reaction is that there is no need to isolate intermediate imines, in par...
ChemInform Abstract: CATALYTIC HYDROGENATION OF ,β-ETHYLENE ALDEHYDES AND KETONES USING CARBONYLCOBALT COMPLEXES UNDER OXO SYNTHESIS CONDITIONSreduction, hydrogenationNo abstract is available for this article.doi:10.1002/chin.197609102EUGENEUCCIANIRICHARD...
Carrier-bound ruthenium catalysts are used to produce alcohols by the catalytic hydrogenation of aldehydes and ketones. The problem of deactivation of the catalyst is solved by the use of a ruthenium
Catalytic Meerwein-Ponndorf-Verley (MPV) reduction of various aliphatic, aromatic, and unsaturated aldehydes and ketones to corresponding alcohols (analyzed by GC-MS) in the presence of boron triethoxide (B(OEt)3) were studied. Kinetics of this reduction
We report an operationally convenient room temperature hydroboration of aldehydes and ketones employing Fe(acac) 3 as precatalyst. The hydroboration of aldehydes and ketones proceeded efficiently at room temperature to yield, after work... SR Tamang,M Findlater - 《Journal of Organic Chemistry》 被引...
Carrier-bound ruthenium catalysts are used to produce alcohols by the catalytic hydrogenation of aldehydes and ketones. The problem of deactivation of the catalyst is solved by the use of a ruthenium catalyst on an oxide carrier of the s... T Haas,B Jaeger,J Sauer,... - US 被引量: 39...