Ketones and aldehydes are hydrogenated to the corresponding alcohol or alkyl group, using H2 gas as the stoichiometric reductant, and organometallic ruthenium complexes as the catalysts.バロツクアールモリスフアガンポールジヨセフハウプトマンエリザベスエムシユラフマルセル...
Catalytic and stoichiometric reduction of ketones and aldehydes by the hydridotetracarbonyl ferrate anionalcohols (acyclic compoundsAcetone is catalytically reduced to isopropyl alcohol by carbon monoxide and water in the presence of iron carbonyls and triethylamine at 100掳C and 100 bar. Use of NaOH ...
Catalytic synthesis of aldehydes and ketones under mild conditions using TEMPO/Oxone. Bolm,Magnus,Hildebrand. Organic Letters . 2000C. Bolm,A. S. Magnus,J. P. Hildebrand.Catalytic Synthesis of Aldehydes and Ketones under Mild Conditions Using TEMPO/Oxone. Organic Letters . 2000...
The reductive amination of aldehydes or ketones using Ph(2)SiH(2) or PhSiH(3) has been effectively promoted by the direct use of Bu(2)SnClH-pyridine N-oxide as a catalyst; this method has advantages in terms of its mild conditions and wide application to various carbonyls and amines, in...
The reductive amination of aldehydes and ketones is one of the most useful routes to secondary amines, in which the three components of carbonyl, amine and reductant are easily combined in one pot.1The advantage of this reaction is that there is no need to isolate intermediate imines, in par...
ChemInform Abstract: CATALYTIC HYDROGENATION OF ,β-ETHYLENE ALDEHYDES AND KETONES USING CARBONYLCOBALT COMPLEXES UNDER OXO SYNTHESIS CONDITIONSreduction, hydrogenationNo abstract is available for this article.doi:10.1002/chin.197609102EUGENEUCCIANIRICHARD...
Reductive arylation of aliphatic and aromatic aldehydes with cyanoarenes by electrolysis for the synthesis of alcohols. Org. Lett. 23, 3472–3476 (2021). Article CAS PubMed Google Scholar Zhang, S. et al. Electrochemical arylation of aldehydes, ketones, and alcohols: from cathodic reduction to...
The reductive amination of aldehydes and ketones and the hydrogenation of nitriles: mechanistic aspects and selectivity control. Adv. Synth. Catal. 344, 1037–1057 (2002). 19. Nishimura, S. Handbook of heterogeneous catalytic hydrogenation for organic synthesis (Wiley, 2001). 20. Volkov, A., ...
Potassium Phosphate as a Solid Base Catalyst for the Catalytic Transfer Hydrogenation of Aldehydes and Ketones Potassium triphosphate is a surprisingly active catalyst for the catalytic transfer hydrogenation of carbonyl compounds. A pretreatment at 600 掳C is criti... R Radhakrishan,DM Do,S Jaenicke...
Carrier-bound ruthenium catalysts are used to produce alcohols by the catalytic hydrogenation of aldehydes and ketones. The problem of deactivation of the catalyst is solved by the use of a ruthenium