Biocatalytic C=C bond reduction through carbon nanodot-sensitized regeneration of NADH analogues. Angew. Chem. Int. Ed. 57, 13825–13828 (2018). Article CAS Google Scholar Holá, K. et al. Carbon dots and [FeFe] hydrogenase biohybrid assemblies for efficient light-driven hydrogen evolution. ...
d Gibbs free energy profile for a SOD-like catalytic cycle of C-dot nanozyme with hydroxyl groups. Full size image The whole SOD-like catalytic cycle (Eq. (2)) of a catalytic site consists of two elementary reactions including an oxidation reaction (Eq. (3)) and a reduction reaction (...
The HOMO – LUMO levels were calculated from oxidation and reduction onset resulted from the cyclic voltammogram (see Fig. 3a) using the Eqs. (1) and (2):(1)HOME=−[Eonset,ox+4.66eV](2)LUMO=−[Eonset,red+4.66eV]where Eonset,ox and Eonset,red are the onset of the oxidation and ...
But the point is the same: a dramatic reduction in both embodied and operational carbon emissions over the full life span of a project. It can be a daunting goal, admits Rives Taylor, a principal and codirector of design resilience at Gensler.“Even if you have full net zero carbon ...
Carbon quantum dots Oxygen reduction Photocatalysis Hydrogen peroxide Proton coupled electron transfer 1. Introduction Hydrogen peroxide (H2O2), a vital green oxidant, has been extensively used in various fields, including textile printing and dyeing, chemical industry, environmental treatment, biomedicine, ...
In order to mitigate global warming, the international communities actively explore low-carbon and green development methods. According to the Paris Agreem
(OER) and oxygen reduction reaction (ORR) are essential for the charging and discharging processes, which determine the overall energy efficiency of ZABs. Since both OER and ORR undergo four electron transfer processes, their extremely slow proton coupling and electron transfer kinetics limit the ...
oryzae[25, 49, 50] hyphal diameters were shown to linearly correlate with the specific growth rate, hence the reduction of hyphal diameters reflects the slow rate of secondary growth during the starvation phase. Focusing on non-empty compartments, we analyzed hyphal population dynamics from ...
et al. Engineering the Nanoscale Morphology of a Quantum Dot-Fullerene Assembly via Complementary Hydrogen Bonding Interactions. Langmuir 29, 7534–7537 (2013). CAS PubMed Google Scholar Zheng, H. Z. et al. Enhancing the luminescence of carbon dots with a reduction pathway. Chem. Commun. 47...
In addition, an increase of nasA and narG abundances could suggest an enhanced assimilatory nitrate reduction to ammonium (ANRA) under eCO2. Therefore, the abundance of commonly responsive functional genes appeared to be directionally related with ecosystem functions under eCO2. Download: Download ...