Arunan, E. Hydrogen bond seen, halogen bond defined and carbon bond proposed: intermolecular bonding, a field that is maturing! Curr. Sci. 2013, 105, 892-894.Arunan E 2013 Hydrogen bond seen, halogen bond defined and carbon bond proposed: Intermolecular bonding, a field that is maturing!; ...
One-to-one hydrogen bonding between hydrogen donors and the isocyanide group is demonstrated by infrared and nuclear magnetic resonance spectra and concentration dependencies of the bonded species. Electronic and steric arguments as well as experimental evidence are presented to prove that the hydrogen bo...
Ab initio and atoms in molecules (AIM) theoretical studies have been used to show that in a 1:1 complex formed between CH 4 and H 2O, CH 4 acting as a hydrogen bond acceptor leads to the global minimum structure. There is a bond path connecting C to the H of H 2O revealing a ...
Carbon dioxide hydrogenation to methane, or methanation of carbon dioxide, also known as the Sabatier reaction, is the hydrogenation of carbon dioxide with hydrogen to form methane. From: Journal of Environmental Chemical Engineering, 2021 About this pageSet alert Also in subject area: EngineeringDisc...
Hydrogen Bonding as a Construction Element for Bidentate Donor Ligands in Homogeneous Catalysis: Regioselective Hydroformylation of Terminal Alkenes A new concept for the construction of bidentate ligands for homogeneous metal complex catalysis is described. The concept relies on the self-assembly of mo...
Molecular structure and chemical bonding properties of atoms depend on the hybrid orbitals’ geometry [17]. 2.1.1 Tetravalent Carbon and Hybridization The electronic configuration of carbon at ground state is 1s2, 2s2, and 2p2. So with four valence shells, electrons are expected to form four ...
(−25 to −75 °C), due to the complex carbon microenvironment around acid sites. It was reported that the main interaction of the probe molecule (15N ACN) with the hydroxy (in zeolite) is via a N···H–O type hydrogen bond to the Brønsted proton. Until recently, the ...
The structure, properties and tribological behavior of DLC films are dependent on the deposition process, the hydrogen concentration and chemical bondings in the films. The present paper reports selected tribological experiments on model DLC films with different hydrogen contents. The experiments were per...
The range of bond length changes starting from the lowest value, 1.10 Å, which corresponds to the length of the carbon–hydrogen bond in fulleranes and fullerynes, until the maximum value, 1.57 Å, related to carbon–carbon bonding in fulleranes. The lengths of the single and triple ...
Quantitative study of C—H bonding in polymerlike amorphous carbon films usingin situinfrared ellipsometry Drevillon, B., Godet, C., Bouree, J.E.: Quantitative study of C-H bonding in polymerlike amorphous carbon films using in situ infrared ellipsometry... T.,Heitz,B.,... - 《Physical ...