only a fraction of first-generation RO2can undergo cyclobutyl ring breaking, a necessary step for further autoxidation and formation of HOM-RO234. This suggests a fixed yield of RO2that can undergo autoxidation. The non-linear effect of NO ...
Neutral Alcohols Only Tend To Undergo Reactions With Very Reactive Electrophiles The Conjugate Acid of An Alcohol Is A Better Electrophile The Conjugate Base of An Alcohol Is A Better Nucleophile Summary: Making Alcohols More Reactive Notes 1. Reviewing Two Earlier Reactions Of Alcohols: Addition To...
I can apply a knowledge of the rate equations for the hydrolysis of halogenoalkanes to deduce the mechanisms for primary and tertiary halogenoalkane hydrolysis and to deduce the mechanism for the reaction between propanone and iodine (4.3h) primary and tertiary halogenoalkane hydrolysis = nucleophil...
Stevens JL, Northcott GL, Stern GA et al (2003) PAHs, PCBs, PCNs, organ- ochlorine pesticides, synthetic musks, and polychlorinated n-alkanes in UK sewage sludge: survey results and implications. Environ Sci Technol 37(3):462–467 100. Wild SR, Waterhouse KS, McGrath SP, Jones KC (...
Such compounds may include pesticides, alkanes, aromatic hydrocarbons, or bisphenol A (Harms et al. 2011). The secretion of LMEs outside the cell gives fungi access to nonpolar and insoluble substances (Llorca et al. 2017). Meanwhile, the presence of functional groups such as amine, hydroxyl,...
Raw woody biomass can be directly converted into liquid alkanes over Pt/NbOPO4 catalyst in cyclohexane medium, with cellulose, hemicellulose and lignin fractions in solid woods being converted into hexanes, pentanes and alkylcyclohexanes, respectively. The red rectangle indicates the β-O-4 linkage...