近日,上海交通大学生命科学技术学院、微生物代谢国家重点实验室邓子新团队合作于《自然通讯》(Nature Communications)杂志上发表题为 “聚酮合酶的碳-氮键形成”(C-N bond formation by a polyketide synthase)的研究论文。该工作通过组合...
相关工作以“Aqueous pulsed electrochemistry promotes C-N bond formation via a one-pot cascade approach”为题发表在国际著名期刊Nature Communications上。 研究要点要点1.作者通过选择经典的Chan-Lam耦合作为模型,报道了一种脉冲电位技术促进NO2-和芳基硼酸在水性电解质中,通过一锅两步级联高产率转化为芳酰胺。主要...
C‐N bond formationC-N bond formationdoi:10.1002/9783527809080.cataz03739C. SlobyAmerican Cancer Society
近日,上海交通大学生命科学技术学院、微生物代谢国家重点实验室邓子新团队合作于《自然通讯》(Nature Communications)杂志上发表题为 “聚酮合酶的碳-氮键形成”(C-N bond formation by a polyketide synthase)的研究论文。上海交大博士后王嘉良、上海佶凯星生物科技有限公司汪小杰、上海交大硕士李希希、国家蛋白... 近日...
During the formation of the carbon tetrahedral intermediate, H372, K367, L437, and L439 may perform the 3-HAA positioning function (Fig. 4g). The mechanism of polyketide chain release by C–N bond formation or thioester hydrolysis identified in this study indicates the catalytic versatility of...
1 In the report, the formation of a new C-N bond has been presumed according to the chemical shifts of the 13C signals originated from the en units in their 13C NMR spectra: one of the signals assigned to the en carbon atoms, which is presumably corresponding to the carbon atom ...
2. Regioselective NiH-catalyzed C–N bond formation of alkenes 3. NiH-catalyzed regioselective C–N bond formation of alkynes 4. Advancements in asymmetric hydroamination and hydroamidation of alkenes 5. Conclusions and outlook Author contributions Conflicts of interest Acknowledgments ReferencesShow full ...
Transition-metal-catalysed, non-enzymatic transformations of C–H and C=C bonds to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable amine building blocks. Although the first examples of racemic NT were reported mo
胡跃飞,林国强 - 现代有机反应.第二卷,碳-氮键的生成反应.Vol.2,= C-N bond formation 被引量: 0发表: 2008年 现代有机反应 . 第九卷 , 碳-氮键的生成反应 . Vol.9 , C-N bond formation . Ⅱ 胡跃飞,林国强 - 现代有机反应 . 第九卷 , 碳-氮键的生成反应 . Vol.9 , C-N bond form...
Buchwald, Pratical palladium catalyst for C–N and C–O bond formation, in: N. Miyaura (Ed.), Cross-Coupling Reactions, Springer, Berlin Heidelberg, 2002, pp. 131–209. [27] L. Jiang, S.L. Buchwald, Palladium-catalyzed aromatic carbon–nitrogen bond formation, in: A. Meijere, F. ...