Iron-catalyzed C–H bond activation followed by C–C bond formation has received much attention in recent years, motivated by the environmental and economical merits of iron, as well as the scientific challenge in controlling and understanding the reactivity of iron species. This review describes ...
C–H bond activation in transition metal species from a computational perspective. Chem. Rev. 110, 749–823 (2010). This review analyses various mechanistic manifolds of transition metal-catalysed C–H activation in detail and classifies these based on computational investigations. Google Scholar ...
Ruthenium(II)-catalyzed C-H bond activation and functionalization (Review) The catalytic functionalization of unreactive C-H Arockiam,B P.,Bruneau,... - 《Chemical Reviews》 被引量: 98发表: 2012年 Synthesis of Electrophilic Rhodium and Iridium Complexes and Investigation of Reactivity for C-H ...
Asymmetric catalytic carbon–carbon coupling reactions via C–H bond activationorganic chemistry, reviewC-C bond formationdiastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism)Review: ca. 100 refs.doi:10.1002/chin.201234213...
ChemInform Abstract: C‐H Bond Activation in Hydrocarbon Oxidation on Solid Catalystsorganic chemistry, reviewoxidation, dehydrogenation, ozonolysis... R Burch,MJ Hayes - 《Chem Inform》 被引量: 0发表: 1996年 ChemInform Abstract: Borylnitrenes: Electrophilic Reactive Intermediates with High Reactivity To...
Iridium-catalyzed sequential silylation and borylation of heteroarenes cased on regioselective C–H bond activation. Angew. Chem. Int. Ed. 57, 5843–5847 (2018). Article CAS Google Scholar Das, S., Incarvito, C. D., Crabtree, R. H. & Brudvig, G. W. Molecular recognition in the ...
oxidativeadditionwithelectronrichlatetransitionmetalsσ-bondmetathesiswithearlytransitionmetalselectrophilicactivationwithelectrondeficientlatetransitionmetals 1.INTRODUCTION oxidativeadditionwithelectronrichlatetransitionmetals σ-bondmetathesiswithearlytransitionmetals electrophilicactivationwithelectron...
CH金属C键金属活化CCH键bond键BondCH键活化键活化 系统标签: activationbondorganometallic活化金属有机化合物 C-HBondActivation:AnIntroduction1GoldmanandGoldberg ACSSymposiumSeries885,ActivationandFunctionalizationofC-HBonds,2004,1-43 OrganometallicC-HBondActivation: AnIntroduction AlanS.Goldman 1 andKarenI.Goldberg...
Chemical transformations via catalytic C H bond activation have been established as one of the most powerful tools in organic synthetic chemistry. Transition-metal-catalyzed addition reactions of C H bonds to polar C X (X = N, O) multiple bonds, such as aldehydes, ketones, imines, isocyanates...
(S)C(SiMe3)CHO}] (4), and [Os3(CO)9(μ3-S){μ3-η2-(Me3Si)CCCCFc}] (5) were obtained from the reaction of FcCCSCCSiMe3 with the activated cluster Os3(CO)10(NCMe)2, as a result of S−C and C−H bond activation as well as C−C coupling reactions in the thioether...